NDLI: Nanochemistry and supramolecular chemistry of actinides and lanthanides: Problems and prospects

Content Provider	Springer Nature Link
Author	Tsivadze, A. Yu. Iova, G. V. Mikhalko, V. K.
Copyright Year	2010
Abstract	The possibility of using unique properties of lanthanides in the nanotechnology is demonstrated. The origination of linear and nonlinear optical properties of lanthanide compounds with phthalocyanines, porphyrins, naphthalocyanines, and their analogs in solutions and condensed state and the prospects of obtaining novel materials on their basis are discussed. Based on the electronic structure and properties of lanthanides and their compounds, namely, optical and magnetic characteristics, electronic and ionic conductivity, and fluctuating valence, molecular engines are classified. High-speed storage engines or memory storage engines; photoconversion molecular engines based on Ln(II) and Ln(III); electrochemical molecular engines involving silicate and phosphate glasses; molecular engines whose operation is based on insulatorsemiconductor, semiconductor-metal, and metal-superconductor types of conductivity phase transitions; solid electrolyte molecular engines; and miniaturized molecular engines for medical analysis are distinguished. It is shown that thermodynamically stable nanoparticles of Ln$_{x}$M$_{y}$ composition can be formed by d elements of the second halves of the series, i.e., those arranged after M = Mn, Tc, and Re. Prospects of using lanthanide superconductors in nanotechnology are considered.
Starting Page	149
Ending Page	169
Page Count	21
File Format	PDF
ISSN	20702051
Journal	Protection of Metals
Volume Number	46
Issue Number	2
e-ISSN	2070206X
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2010-04-07
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Characterization and Evaluation of Materials Industrial Chemistry/Chemical Engineering Inorganic Chemistry Metallic Materials Materials Science Tribology, Corrosion and Coatings
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Surfaces, Coatings and Films Materials Chemistry Metals and Alloys

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