NDLI: Steady-state anodic dissolution of iron in neutral and close-to-neutral media

Content Provider	Springer Nature Link
Author	Podobaev, A. N. Reformatskaya, I. I. Aleksanyan, A. Yu.
Copyright Year	2007
Abstract	In neutral and close-to-neutral solutions, which contain no surface-active substances, iron dissolves via a two-step scheme. The transfer of the first electron across the interface involves water molecules that dissociate during the adsorption; the transfer of the second electron limits the process under steady-state conditions. In parallel, a passivator, namely, adsorbed oxygen is formed via a similar scheme. The passivator is removed from the surface due to its chemical reaction with hydroxonium ions, water molecules, or hydroxide ions. The process is adequately described by a mathematical model based on an assumption that the metal dissolves from an energy-uniform surface free from passivating species.
Ending Page	69
Page Count	4
Starting Page	66
File Format	PDF
ISSN	00331732
e-ISSN	1608327X
Journal	Protection of Metals
Issue Number	1
Volume Number	43
Language	English
Publisher	Nauka/Interperiodica
Publisher Date	2007-01-01
Publisher Place	Moscow
Access Restriction	Subscribed
Subject Keyword	Materials Science Tribology, Corrosion and Coatings Inorganic Chemistry Metallic Materials Industrial Chemistry/Chemical Engineering Characterization and Evaluation Materials
Content Type	Text
Resource Type	Article

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Steady-state anodic dissolution of iron in neutral and close-to-neutral media