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  1. Origins of Life and Evolution of Biospheres
  2. Origins of Life and Evolution of Biospheres : Volume 40
  3. Origins of Life and Evolution of Biospheres : Volume 40, Issue 1, February 2010
  4. Homochirality and the Need for Energy
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Origins of Life and Evolution of Biospheres : Volume 47
Origins of Life and Evolution of Biospheres : Volume 46
Origins of Life and Evolution of Biospheres : Volume 45
Origins of Life and Evolution of Biospheres : Volume 44
Origins of Life and Evolution of Biospheres : Volume 43
Origins of Life and Evolution of Biospheres : Volume 42
Origins of Life and Evolution of Biospheres : Volume 41
Origins of Life and Evolution of Biospheres : Volume 40
Origins of Life and Evolution of Biospheres : Volume 40, Issue 6, December 2010
Origins of Life and Evolution of Biospheres : Volume 40, Issue 4-5, October 2010
Origins of Life and Evolution of Biospheres : Volume 40, Issue 3, June 2010
Origins of Life and Evolution of Biospheres : Volume 40, Issue 2, April 2010
Origins of Life and Evolution of Biospheres : Volume 40, Issue 1, February 2010
On the Emergence of Biochemical Homochirality: An Elusive Beginning
Stereoselective Syntheses of Pentose Sugars Under Realistic Prebiotic Conditions
Imitating Prebiotic Homochirality on Earth
Chiral Biases in Solids by Effect of Shear Gradients: A Speculation on the Deterministic Origin of Biological Homochirality
Amplification of Chirality at Solid Surfaces
Dual Role of Hydrophobic Racemic Thioesters of α-Amino Acids in the Generation of Isotactic Peptides and Co-peptides in Water; Implications for the Origin of Homochirality
Asymmetric Autocatalysis Induced by Chiral Crystals of Achiral Tetraphenylethylenes
Spontaneous Mirror Symmetry Breaking in the Aldol Reaction and its Potential Relevance in Prebiotic Chemistry
Homochirality and the Need for Energy
Homochirality in Life: Two Equal Runners, One Tripped
Origins of Life and Evolution of Biospheres : Volume 39
Origins of Life and Evolution of Biospheres : Volume 38
Origins of Life and Evolution of Biospheres : Volume 37
Origins of Life and Evolution of Biospheres : Volume 36
Origins of Life and Evolution of Biospheres : Volume 35
Origins of Life and Evolution of Biospheres : Volume 34
Origins of Life and Evolution of Biospheres : Volume 33
Origins of Life and Evolution of Biospheres : Volume 32
Origins of Life and Evolution of Biospheres : Volume 31
Origins of Life and Evolution of Biospheres : Volume 30
Origins of Life and Evolution of Biospheres : Volume 29
Origins of Life and Evolution of Biospheres : Volume 28
Origins of Life and Evolution of Biospheres : Volume 27

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Homochirality and the Need for Energy

Content Provider Springer Nature Link
Author Plasson, Raphaël Brandenburg, Axel
Copyright Year 2009
Abstract The mechanisms for explaining how a stable asymmetric chemical system can be formed from a symmetric chemical system, in the absence of any asymmetric influence other than statistical fluctuations, have been developed during the last decades, focusing on the non-linear kinetic aspects. Besides the absolute necessity of self-amplification processes, the importance of energetic aspects is often underestimated. Going down to the most fundamental aspects, the distinction between a single object—that can be intrinsically asymmetric—and a collection of objects—whose racemic state is the more stable one—must be emphasized. A system of strongly interacting objects can be described as one single object retaining its individuality and a single asymmetry; weakly or non-interacting objects keep their own individuality, and are prone to racemize towards the equilibrium state. In the presence of energy fluxes, systems can be maintained in an asymmetric non-equilibrium steady-state. Such dynamical systems can retain their asymmetry for times longer than their racemization time.
Starting Page 93
Ending Page 110
Page Count 18
File Format PDF
ISSN 01696149
Journal Origins of Life and Evolution of Biospheres
Volume Number 40
Issue Number 1
e-ISSN 15730875
Language English
Publisher Springer Netherlands
Publisher Date 2009-11-13
Publisher Place Dordrecht
Access Restriction Subscribed
Subject Keyword Emergence of homochirality Energy Entropy Non-equilibrium thermodynamics System chemistry Symmetry breaking Biochemistry Astronomy, Observations and Techniques Earth Sciences Astrophysics and Astroparticles Life Sciences
Content Type Text
Resource Type Article
Subject Medicine Ecology, Evolution, Behavior and Systematics Space and Planetary Science
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