NDLI: Oligomerization of α-Thioglutamic Acid

Content Provider	Springer Nature Link
Author	Maurel, Marie Christine Orgel, Leslie E.
Copyright Year	2000
Abstract	A decaglutamic acid primer is extended very slowly byα-thioglutamic acid. The addition of bicarbonate to thereaction mixture greatly accelerates the reaction. We believethe N-carboxyanhydride of glutamic acid is an intermediate inthe accelerated reaction. When K$_{3}$Fe(CN)$_{6}$ andbicarbonate are both present in the reaction mixture,oligoglutamic acids up to at least the 15-mer are formedrapidly. The acylating agent is the oxidation product ofthioglutamic acid, a diacyldisulfide.
Starting Page	423
Ending Page	430
Page Count	8
File Format	PDF
ISSN	01696149
Journal	Origins of Life and Evolution of Biospheres
Volume Number	30
Issue Number	5
e-ISSN	15730875
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2000-01-01
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	Organic Chemistry Geochemistry Biochemistry
Content Type	Text
Resource Type	Article
Subject	Medicine Ecology, Evolution, Behavior and Systematics Space and Planetary Science

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Oligomerization of α-Thioglutamic Acid