NDLI: Tunable synthesis of propylene glycol ether from methanol and propylene oxide under ambient pressure

Content Provider	Springer Nature Link
Author	Bai, Yu Cai, Qinghai Wang, Xiaoguang Lu, Bin
Copyright Year	2011
Abstract	A series of basic and acidic ionic liquids, 1-butyl-3-methylimidazolium hydroxide (BMIMOH), 1-acetyl-3-methylimidazolium chloride (AcMIMCl) and AcMIMCl-FeCl$_{3}$, or analogues of AcMIMCl, namely 1-potassium acetate-3-methylimidazolium chloride (KAcMIMCl), 1-potassium (sodium, ammonium) acetate-3-methylimidazolium hydroxides (KAcMIMOH, NaAcMIMOH and NH$_{4}$AcMIMOH), were prepared and used as catalysts for catalytic synthesis of propylene glycol ether via reaction of propylene oxide (PO) with methanol under mild reaction conditions. KAcMIMOH exhibited outstanding catalytic performance with 94.2% of conversion of PO and 99.1% of selectivity to 1-methoxy-2-propanol (MP-2) at 60°C and ambient pressure for 4 h. However, AcMIMCl-FeCl$_{3}$ showed a good catalysis performance with high selectivity to 2-methoxy-1-propanol (MP-1). The tunable synthesis of MP-2 or MP-1 catalyzed by basic compound KAcMIMOH or acidic ionic liquid AcMIMCl-FeCl$_{3}$ was realized.
Starting Page	386
Ending Page	390
Page Count	5
File Format	PDF
ISSN	00231584
Journal	Kinetics and Catalysis
Volume Number	52
Issue Number	3
e-ISSN	16083210
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2011-06-08
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis Modeling and Simulation Computer Science Applications

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Kinetics of propylene glycol hydrochlorination

Synthesis of Propylene Glycol Monomethyl Ether Over Mg/Al Hydrotalcite Catalyst

Immobilized 1,1,3,3-Tetramethylguanidine Ionic Liquids as the Catalyst for Synthesizing Propylene Glycol Methyl Ether

Synthesis of gasoline from syngas via dimethyl ether

Kinetics of propylene epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite in methanol

Modified Zinc Oxide for the Direct Synthesis of Propylene Carbonate from Propylene Glycol and Carbon dioxide

Kinetics and mechanism of the catalytic hydration of propylene oxide

Nickel oxide reduction under nonisothermal conditions

One-Pot Synthesis of Dimethyl Carbonate from Methanol, Propylene Oxide and Carbon Dioxide Over Supported Choline hydroxide/MgO

Tunable synthesis of propylene glycol ether from methanol and propylene oxide under ambient pressure

Similar Documents

Kinetics of propylene glycol hydrochlorination

Synthesis of Propylene Glycol Monomethyl Ether Over Mg/Al Hydrotalcite Catalyst

Immobilized 1,1,3,3-Tetramethylguanidine Ionic Liquids as the Catalyst for Synthesizing Propylene Glycol Methyl Ether

Synthesis of gasoline from syngas via dimethyl ether

Kinetics of propylene epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite in methanol

Modified Zinc Oxide for the Direct Synthesis of Propylene Carbonate from Propylene Glycol and Carbon dioxide

Kinetics and mechanism of the catalytic hydration of propylene oxide

Nickel oxide reduction under nonisothermal conditions

One-Pot Synthesis of Dimethyl Carbonate from Methanol, Propylene Oxide and Carbon Dioxide Over Supported Choline hydroxide/MgO

Tunable synthesis of propylene glycol ether from methanol and propylene oxide under ambient pressure