NDLI: Solid-state Decompositions — Stagnation or Progress?

Content Provider	Springer Nature Link
Author	Galwey, A. K. Brown, M. E.
Copyright Year	2000
Abstract	An appraisal of the trends discerned in the recent literature concerned with solid-state decompositions suggests that this research area lacks a general theoretical framework and, hence, order in the subject is difficult to recognize. There have been surprisingly few reviews of the field. Many of the continuing flow of research publications may be of individual value, but most do not contribute to the overall development of the topic. For example, in many studies of reversible dissociations the sensitivity of rate characteristics to prevailing conditions is not discussed so that the fit of data to rate equations and the magnitudes of calculated Arrhenius parameters may be of empirical value only. Some studies report kinetic results without mechanistic discussions supported by complementary observations. Progress forward from an apparent state of stagnation depends upon more critical examination of the existing literature, coupled with better designed experiments to establish the reproducibility and reliability of kinetic conclusions. Techniques capable of providing insights into the bond redistribution steps that occur during reactions in crystals are also urgently needed.
Starting Page	863
Ending Page	877
Page Count	15
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	60
Issue Number	3
e-ISSN	15728943
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2000-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Physical Chemistry Polymer Sciences Measurement Science, Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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