NDLI: Thermal decomposition of [Cd(NH$_{3}$)$_{6}$](NO$_{3}$)$

Content Provider	Springer Nature Link
Author	Mikuli, E. Liszka, M. Molenda, M.
Copyright Year	2007
Abstract	Thermal decomposition of [Cd(NH$_{3}$)$_{6}$](NO$_{3}$)$_{2}$ was studied by thermogravimetry (TG) with simultaneous differential thermal analysis (SDTA) for two samples and at two different sets of measurement parameters. The gaseous products of the decomposition were on-line identified by evolved gas analysis (EGA) with a quadruple mass spectrometer (QMS). The decomposition of the title compound proceeds, for both cases, in the three main stages. In the first stage, deammination of [Cd(NH$_{3}$)$_{6}$](NO$_{3}$)$_{2}$ to [Cd(NH$_{3}$)](NO$_{3}$)$_{2}$ undergoes by three steps and 5/6 of all NH$_{3}$ molecules are liberated. At second stage the liberation of residual 1/6NH$_{3}$ molecules and the formation of Cd(NO$_{3}$)$_{2}$ undergoes. However, during this process simultaneously a two-step oxidation of a part of ammonia molecules also takes place. In a first step as a result a mixture of ammonia, water vapour and nitrogen is formatted. At the second step, subsequent oxidation of a next part of NH$_{3}$ molecules undergoes. As a result, a mixture of nitrogen oxide, nitrogen and water vapour is formatted, what for these both steps clearly indicates the EGA analysis. The third stage of the thermal decomposition is connected with the melting and subsequent decomposition of residual Cd(NO$_{3}$)$_{2}$ to oxygen, nitrogen dioxide and solid CdO. Additionally, third sample was measured by differential scanning calorimetry (DSC) and the results are fully consistent with those obtained by TG.
Starting Page	573
Ending Page	578
Page Count	6
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	89
Issue Number	2
e-ISSN	15728943
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2007-07-19
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	DSC EGA hexaamminecadmium(II) nitrate(V) SDTA TG thermal decomposition Measurement Science, Instrumentation Inorganic Chemistry Physical Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Phase transition and thermal decomposition of [Al(DMSO)$_{6}$]Cl$_{3}$

Thermal behaviour of [Mg(DMSO)$_{6}$](NO$_{3}$)$_{2}$

Thermal behaviour of [Ca(H$_{2}$O)$_{4}$](NO$_{3}$)$_{2}$

Phase polymorphism and thermal decomposition of hexadimethylsulphoxidemagnesium(II) chlorate(VII)

Polymorphism and thermal decomposition of [Ni(DMSO)$_{4}$]I$_{2}$

Thermal properties, phase transitions, vibrational and reorientational dynamics of [Mn(NH$_{3}$)$_{6}$](NO$_{3}$)$_{2}$

The thermal decomposition of silver dinitramide AgN(NO$_{2}$)$_{2}$

Investigations on NH$_{4}$VO$_{3}$ thermal decomposition in dry air

Melting behaviour and evolved gas analysis of xylose

Thermal decomposition of [Cd(NH$_{3}$)$_{6}$](NO$_{3}$)$_{2}$

Similar Documents

Phase transition and thermal decomposition of [Al(DMSO)$_{6}$]Cl$_{3}$

Thermal behaviour of [Mg(DMSO)$_{6}$](NO$_{3}$)$_{2}$

Thermal behaviour of [Ca(H$_{2}$O)$_{4}$](NO$_{3}$)$_{2}$

Phase polymorphism and thermal decomposition of hexadimethylsulphoxidemagnesium(II) chlorate(VII)

Polymorphism and thermal decomposition of [Ni(DMSO)$_{4}$]I$_{2}$

Thermal properties, phase transitions, vibrational and reorientational dynamics of [Mn(NH$_{3}$)$_{6}$](NO$_{3}$)$_{2}$

The thermal decomposition of silver dinitramide AgN(NO$_{2}$)$_{2}$

Investigations on NH$_{4}$VO$_{3}$ thermal decomposition in dry air

Melting behaviour and evolved gas analysis of xylose

Thermal decomposition of [Cd(NH$_{3}$)$_{6}$](NO$_{3}$)$_{2}$