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| Content Provider | Springer Nature Link |
|---|---|
| Author | Rajasekar, M. Muthu, K. Meenatchi, V. Meenakshisundaram, S. P. Mojumdar, S. C. |
| Copyright Year | 2013 |
| Abstract | A new semiorganic single crystal, tris(allylthiourea)silver(I) nitrate was grown from an aqueous solution containing silver(I) nitrate and allylthiourea by slow evaporation solution growth technique at room temperature. The crystal belongs to trigonal system with centrosymmetric space group R3 and the cell parameters are, a = 12.5090(4) Å, b = 12.5090(4) Å, c = 21.7130(8) Å, V = 3348.89 Å$^{3}$, and Z = 6. The various functional groups present in the molecule are confirmed by Fourier transformed infrared spectroscopy. High transmittance is observed in the visible region and band-gap energy is calculated by Kubelka–Munk algorithm. The structure and the crystallinity of the materials were further confirmed using powder X-ray diffraction analysis. Microhardness studies were also carried out to elucidate the mechanical behavior. Thermogravimetric and differential thermal analysis reveal the purity of the sample and no decomposition is observed up to the melting point. |
| Starting Page | 1107 |
| Ending Page | 1112 |
| Page Count | 6 |
| File Format | |
| ISSN | 13886150 |
| Journal | Journal of thermal analysis |
| Volume Number | 112 |
| Issue Number | 2 |
| e-ISSN | 15728943 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2013-03-26 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Allylthiourea complex Thermal analysis Mechanical studies X-ray diffraction Optical studies Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Condensed Matter Physics |
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