NDLI: Discriminating within the kinetic models for heterogeneous processes of materials by employing a combined procedure under TKS-SP 2.0 software

Content Provider	Springer Nature Link
Author	Rotaru, Andrei
Copyright Year	2016
Abstract	Kinetics of heterogeneous processes of materials is an important topic of thermal analysis field; it directly describes the dynamics of condensed matter systems, revealing “hot insights” of materials towards a better understanding of their structural, functional and transition-related properties. The advanced thermal and kinetic software by standard procedure TKS-SP 2.0 was successfully employed to perform kinetic computations, by making use of an extended spectrum of procedures, methods and discrimination criteria, it produces in real-time, high-volume and accurate sets of kinetic data from thermally induced processes. The discrimination between the kinetic models and the selection of the appropriate one is explained here in an in-depth study, employing the Perez-Maqueda et al. criterion under both integral and differential procedures in combination with the Gotor et al. master plots method. Perez-Maqueda et al. criterion describes the independence of the kinetic parameters from the heating rate, while the master plots method of Gotor et al. give the fastest way to check the kinetic models just by fitting in a continuous and visual manner the normalised transformation rate of a chemical or physical process with the relation ([f(α)·g(α)]/[f(α $_{max}$)·g(α $_{max}$)])—where the adjustment of the step of the kinetic model and of the values for the conversion degree at the maximal conversion rate inside the relation is performed. A working procedure is proposed to be applied for the step-by-step evaluations, discrimination and selection of the unique kinetic triplet {E, A, f(α)} corresponding to a certain investigated process.
Starting Page	919
Ending Page	932
Page Count	14
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	126
Issue Number	2
e-ISSN	15882926
Language	English
Publisher	Springer Netherlands
Publisher Date	2016-05-31
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Gotor et al. master plots Heterogeneous processes Kinetic models Kinetic software Perez-Maqueda et al. criterion TKS-SP 2.0 Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Computational thermal and kinetic analysis : Complete standard procedure to evaluate the kinetic triplet form non-isothermal data

Computational thermal and kinetic analysis : Software for non-isothermal kinetics by standard procedure

Thermokinetic study of CODA azoic liquid crystal and thin films deposition by matrix-assisted pulsed laser evaporation

Thermal decomposition kinetics of some aromatic azomonoethers : Part III. Non-isothermal study of 4-[(4-chlorobenzyl)oxy]-4′-chloroazobenzene in dynamic air atmosphere

Thermal decomposition kinetics of some aromatic azomonoethers : Part IV. Non-isothermal kinetics of 2-allyl-4-((4-(4-methylbenzyloxy)phenyl)diazenyl)phenol in air flow

The Ozawa’s generalized time concept and YZ-master plots as a convenient tool for kinetic analysis of complex processes

Generalized Kinetic Master Plots for the Thermal Degradation of Polymers Following a Random Scission Mechanism

Estimation of the kinetic characteristics of sorption of an organic ion on a heterogeneous crosslinked polymer sorbent within the framework of a bidisperse model

Effect of sucrose on BSA denatured aggregation at high concentration studied by the iso-conversional method and the master plots method

Discriminating within the kinetic models for heterogeneous processes of materials by employing a combined procedure under TKS-SP 2.0 software

Similar Documents

Computational thermal and kinetic analysis : Complete standard procedure to evaluate the kinetic triplet form non-isothermal data

Computational thermal and kinetic analysis : Software for non-isothermal kinetics by standard procedure

Thermokinetic study of CODA azoic liquid crystal and thin films deposition by matrix-assisted pulsed laser evaporation

Thermal decomposition kinetics of some aromatic azomonoethers : Part III. Non-isothermal study of 4-[(4-chlorobenzyl)oxy]-4′-chloroazobenzene in dynamic air atmosphere

Thermal decomposition kinetics of some aromatic azomonoethers : Part IV. Non-isothermal kinetics of 2-allyl-4-((4-(4-methylbenzyloxy)phenyl)diazenyl)phenol in air flow

The Ozawa’s generalized time concept and YZ-master plots as a convenient tool for kinetic analysis of complex processes

Generalized Kinetic Master Plots for the Thermal Degradation of Polymers Following a Random Scission Mechanism

Estimation of the kinetic characteristics of sorption of an organic ion on a heterogeneous crosslinked polymer sorbent within the framework of a bidisperse model

Effect of sucrose on BSA denatured aggregation at high concentration studied by the iso-conversional method and the master plots method

Discriminating within the kinetic models for heterogeneous processes of materials by employing a combined procedure under TKS-SP 2.0 software