NDLI: Thermochemistry of Bu$_{4}$NBr solutions in binary solvents containing formamide

Content Provider	Springer Nature Link
Author	Korolev, V. P. Antova, O. A. Smirva, N. L. Kustov, A. V.
Copyright Year	2009
Abstract	The heats of solution of tetrabutylammonium bromide have been measured in mixtures of formamide (FA) with methanol (MeOH) and ethylene glycol (EG) at 313.15 K by calorimetric method. The standard enthalpies of solution in binary mixtures have been extrapolated to infinite dilution by Redlich–Rosenfeld–Meyer type equation using the literary data at 298.15 K and the present paper data at 313.15 K. The Debye–Hückel limiting law slope A $_{H}$ required for calculation of the ∆$_{sol}$ H $^{0}$ value has been obtained with application the new additive scheme of determination of the physic-chemical characteristics of binaries. The scheme is tested on the example of Bu$_{4}$NBr solutions in FA–MeOH mixture at 298.15 K. Its application yields the ∆$_{sol}$ H $^{0}$ value very closed on the ones determined with the real (non-additive) characteristics of binaries. The standard enthalpies of solution extrapolated by Redlich–Rosenfeld–Meyer type equation are in a good agreement with the ones computed in terms of the Debye–Hückel theory in the second approximation. The heat capacities characteristics of Bu$_{4}$NBr have been calculated in H$_{2}$O–FA, MeOH–FA and EG–FA mixtures using the literary and present data. The sequence of solvents H$_{2}$O > FA > EG > MeOH located on their ability to solvophobic solvation found by us earlier for enthalpic characteristics is confirmed by the ∆C $_{p}$ $^{0}$ values. The comparison of thermochemical characteristics of Bu$_{4}$NBr solutions in aqueous and non-aqueous mixtures containing FA has been carried out. The own structure of water remains in the region of small additions of formamide to co-solvents. It considerably differs the H$_{2}$O–FA mixture from the investigated non-aqueous systems.
Starting Page	903
Ending Page	910
Page Count	8
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	96
Issue Number	3
e-ISSN	15728943
Language	English
Publisher	Springer Netherlands
Publisher Date	2009-07-04
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Binary solvent Enthalpy of solution Enthalpy of transfer Ethylene glycol Formamide Heat capacity of solution Methanol Tetrabutylammonium bromide Measurement Science, Instrumentation Inorganic Chemistry Polymer Sciences Analytical Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Thermochemistry of Bu4NBr solutions in binary solvents containing formamide

Thermal properties of n-R$_{4}$NBr solutions in binary solvents containing formamide

Thermal properties of tetraalkylammonium bromides in several solvents

The Enthalpies and Heat Capacities of Solution of Tetraethyl- and Tetrabutylammonium Bromides in Methanol, Formamide, and Ethylene Glycol

“Structure promotion” and “structure breaking”. Heat capacities of caesium bromide, tetramethylammonium bromide and tetra-n-butylammonium bromide in several solvents from 278 to 328 K

Heat properties of Bu$_{4}$NBr solutions in binary mixtures based on formamide

Enthalpies of solution of n-alcohols in formamide and ethylene glycol

Molar heat capacities and solution thermochemistry of n-undecylammonium bromide monohydrate C$_{11}$H$_{28}$BrNO(s)

Thermochemical study of the temperature effect on the l-α-alanine-l-α-alanine interactions in aqueous solutions of urea and ethylene glycol

Thermochemistry of Bu$_{4}$NBr solutions in binary solvents containing formamide

Similar Documents

Thermochemistry of Bu4NBr solutions in binary solvents containing formamide

Thermal properties of n-R$_{4}$NBr solutions in binary solvents containing formamide

Thermal properties of tetraalkylammonium bromides in several solvents

The Enthalpies and Heat Capacities of Solution of Tetraethyl- and Tetrabutylammonium Bromides in Methanol, Formamide, and Ethylene Glycol

“Structure promotion” and “structure breaking”. Heat capacities of caesium bromide, tetramethylammonium bromide and tetra-n-butylammonium bromide in several solvents from 278 to 328 K

Heat properties of Bu$_{4}$NBr solutions in binary mixtures based on formamide

Enthalpies of solution of n-alcohols in formamide and ethylene glycol

Molar heat capacities and solution thermochemistry of n-undecylammonium bromide monohydrate C$_{11}$H$_{28}$BrNO(s)

Thermochemical study of the temperature effect on the l-α-alanine-l-α-alanine interactions in aqueous solutions of urea and ethylene glycol

Thermochemistry of Bu$_{4}$NBr solutions in binary solvents containing formamide