NDLI: Thermokinetic parameters and thermal hazard evaluation for three organic peroxides by DSC and TAM III

Content Provider	Springer Nature Link
Author	Liu, Shang Hao Lin, Chun Ping Shu, Chi Min
Copyright Year	2011
Abstract	The thermokinetic parameters were investigated for cumene hydroperoxide (CHP), di-tert-butyl peroxide (DTBP), and tert-butyl peroxybenzoate (TBPB) by non-isothermal kinetic model and isothermal kinetic model by differential scanning calorimetry (DSC) and thermal activity monitor III (TAM III), respectively. The objective was to investigate the activation energy (E $_{a}$) of CHP, DTBP, and TBPB applied non-isothermal well-known kinetic equation to evaluate the thermokinetic parameters by DSC. We employed TAM III to assess the thermokinetic parameters of three liquid organic peroxides, obtained thermal runaway data, and then used the Arrhenius plot to obtain the E $_{a}$ of liquid organic peroxides at various isothermal temperatures. In contrast, the results of non-isothermal kinetic algorithm and isothermal kinetic algorithm were acquired from a highly accurate procedure for receiving information on thermal decomposition characteristics and reaction hazard.
Starting Page	165
Ending Page	172
Page Count	8
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	106
Issue Number	1
e-ISSN	15728943
Language	English
Publisher	Springer Netherlands
Publisher Date	2011-05-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Differential scanning calorimetry Liquid organic peroxides Reaction hazard Thermal activity monitor III Thermokinetic parameters Measurement Science and Instrumentation Analytical Chemistry Physical Chemistry Inorganic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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