NDLI: Three new dinuclear silver(I) complexes derived from pyrazolyl type ligands : Crystal structure and thermal decomposition

Content Provider	Springer Nature Link
Author	Atakol, O. Fuess, H. Kurtaran, R. Akay, A. Arici, C. Ergun, Ü. Emregül, K. C.
Copyright Year	2007
Abstract	Three NNN type ligands derived from 2,6-dichlorpyroidine, pyrazol and 3,5-dimethylpyrazole and their silver complexes were prepared in methanol media. The complex structures were characterized using IR spectroscopy, X-ray diffraction and elemental analysis. X-ray studies showed the complexes to be dimeric in structure. The two nitrogen atoms of the ligand coordinated the first Ag(I) ion whereas the second Ag(I) ion was coordinated by the third nitrogen donor. The nitrate structure was not ionic in a done of its oxygen atoms coordinated an Ag(I) ion. The Ag(I) ion was seen to be situated in a deformed tetrahedral coordination sphere. Thermogravimetric studies showed the complexes to decompose similar to explosive material. The decomposition temperature was observed to increase with increasing hydrogen atoms in the structure.
Starting Page	517
Ending Page	523
Page Count	7
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	90
Issue Number	2
e-ISSN	15728943
Language	English
Publisher	Springer US
Publisher Date	2007-02-26
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	DTA pyrazolyl silver(I) complex TG Measurement Science, Instrumentation Inorganic Chemistry Physical Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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