NDLI: Enthalpies of mixing of o- and m-isomers at 298.15 K

Content Provider	Springer Nature Link
Author	Kimura, T. Takahashi, Y. Kamiyama, T. Fujisawa, M.
Copyright Year	2007
Abstract	Excess enthalpies (H $^{E}$) of 17 binary mixtures of o- and m-isomers of dichlorobenzene, difluorobenzene, methoxymethylbenzene, dimethylbenzene, dimethoxybenzene, aminofluorobenzene, fluoronitrobenzene, diethylbenzene, chlorofluorobenzene, fluoroiodobenzene, bromofluorobenzene, chloromethylbenzene, fluoromethylbenzene, bromomethylbenzene, iodomethylbenzene, fluoromethoxybenzene, dibromobenzene at 298.15 K were measured. All excess enthalpies measured were very small, and those of o-+m-isomers of aminofluorobenzene, dibromobenzene and iodomethylbenzene were negative but 14 other binary mixtures of isomers were positive over the whole range of mole fractions. H $^{E}$ of o-+m-isomers of dimethoxybenzene showed the largest enthalpic instability and those of aminofluorobenzene showed the largest enthalpic stability. There was a correlation between dipole–dipole interaction, dipole–induced dipole interaction or entropies of vaporization and excess partial molar enthalpies at infinite dilution.
Starting Page	587
Ending Page	595
Page Count	9
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	88
Issue Number	2
e-ISSN	15728943
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2007-05-15
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	dipole–dipole interaction dipole–induced dipole interaction entropy of vaporization excess enthalpy o-, m-isomer structural isomer Polymer Sciences Physical Chemistry Inorganic Chemistry Measurement Science, Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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