NDLI: The Use of Adiabatic Calorimetry for the Process Analysis and Safety Evaluation in Free Radical Polymerization

Content Provider	Springer Nature Link
Author	Maschio, G. Feliu, J. A. Ligthart, J. Ferrara, I. Bassani, C.
Copyright Year	1999
Abstract	Adiabatic calorimetry is a technique that has been introduced as an important approach to hazard evaluation of exothermically reactive systems. In this paper the free radical polymerization of methyl methacrylate (MMA) has been studied. One of the most important aspects of MMA polymerization is its exothermicity and autoaccelerating behaviour, these characteristics can generate the occurrence of a runaway reaction.In a runaway situation the reacting system is close to adiabatic behaviour because it is unable to eliminate the heat that is being generated. An even worse situation can be reproduced in the laboratory with the Phi-Tec pseudo-adiabatic calorimeter. Process design parameters that are usually calculated from thermodynamic data or using semiempirical rules, such as adiabatic temperature rise or maximum attainable pressure, can be directly determined.The existence of the ceiling temperature has been experimentally demonstrated.
Starting Page	201
Ending Page	214
Page Count	14
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	58
Issue Number	1
e-ISSN	15728943
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	1999-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Physical Chemistry Polymer Sciences Measurement Science, Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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