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| Content Provider | Springer Nature Link |
|---|---|
| Author | Lin, C. H. Chang, Y. M. Lee, J. C. Lin, S. Y. Shu, C. M. |
| Copyright Year | 2008 |
| Abstract | Preventing accidental explosions of flammable liquid/gas mixtures is very important. As far as flammability characteristics are concerned, we simulated the effects of inert liquid/gas, which was filled with reactors, vessels, or closed space, employed in the chemical process industries. The inert liquid/gas (H$_{2}$O) weakened the oxygen concentration and reduced solvent vapor concentration in a 20-L-Apparatus. This study investigated the flammability characteristics of acetone/water solutions (100/0, 75/25, 50/50, and 25/75 vol.%) that are controlled at a temperature of 150°C and pressures of 101/202 kPa, respectively. The flammability parameters included flammability limits (LEL and UEL), maximum explosion pressure (P $_{max}$), maximum explosion pressure rise ((dP dt $^{−1}$)$_{max}$), and vapor deflagration index (K $_{g}$). The results of a series of experimental tests showed that UEL, P $_{max}$, and K $_{g}$ all decreased with steam rising under the experimental conditions. The results can be applied to process safety design/operation for identifying whether the inert liquid/gas (H$_{2}$O) content has any substantial effects in reducing the fire and explosion hazard of the solution of interest. |
| Starting Page | 195 |
| Ending Page | 200 |
| Page Count | 6 |
| File Format | |
| ISSN | 13886150 |
| Journal | Journal of thermal analysis |
| Volume Number | 93 |
| Issue Number | 1 |
| e-ISSN | 15728943 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2008-07-01 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | acetone/water solutions explosion accidents flammability parameters inert liquid/gas (H$_{2}$O) 20-L-Apparatus Measurement Science, Instrumentation Inorganic Chemistry Polymer Sciences Analytical Chemistry Physical Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Condensed Matter Physics |
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