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| Content Provider | Springer Nature Link |
|---|---|
| Author | Jung, S. Y. Zhang, G. Yoshida, H. |
| Copyright Year | 2007 |
| Abstract | The concept of crystallization dynamics method evaluating the miscibility of binary blend system including crystalline component was proposed. Three characteristic rates, nucleation, crystal growth rates (N*, G*) and growth rate of conformation (G $_{c}$*) were used to evaluate the miscibility of PVDF/at-PMMA and PVDF/iso-PMMA by the simultaneous DSC-FTIR. N*, G* and G $_{c}$* depended remarkably on both temperature and blend fraction (ϕ$_{PMMA}$) for PVDF/at-PMMA system, which indicated the miscible system. PVDF/iso-PMMA showed small ϕ$_{PMMA}$ dependency of N*, G* and G $_{c}$*, was estimated the immiscible system. The ΔT/T m 0 values, corresponding to Gibbs energy required to attend the constant G* and G $_{c}$*, evaluated from G* and G $_{c}$* showed the good linear relationships with different slope. The experimental results suggested that the concentration fluctuation existed in PVDF/iso-PMMA system. |
| Starting Page | 675 |
| Ending Page | 680 |
| Page Count | 6 |
| File Format | |
| ISSN | 13886150 |
| Journal | Journal of thermal analysis |
| Volume Number | 89 |
| Issue Number | 3 |
| e-ISSN | 15728943 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2007-08-23 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | concentration fluctuation crystallization DSC-FTIR miscibility polymer blend Measurement Science, Instrumentation Inorganic Chemistry Physical Chemistry Polymer Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Condensed Matter Physics |
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