NDLI: Incorporation of Cadmium Ions and Cadmium Sulfide Particles into Sol-gel Zirconium Phosphate. Synthesis, thermal behavior and X-ray characterization

Content Provider	Springer Nature Link
Author	Ferragina, C. Cafarelli, P. Di Rocco, R.
Copyright Year	2001
Abstract	The inorganic ion-exchanger α-zirconium phosphate was synthesized by the sol-gel method and its properties relating to the exchange of Cd$^{2+}$ and the intercalation of CdS particles were studied. The Cd$^{2+}$-exchange process is a fast process and the material obtained exhibits an increased interlayer distance d with respect to its precursor (9.56 vs. 7.56 Å). The resulting Cd-containing material was exposed to aH$_{2}$S gas flow to give CdS particles in the exchanger. The zirconium phosphate containing CdS particles still possesses a layered structure, with a pattern almost identical to that of the initial ion-exchanger precursor. Moreover, the material may exchange further Cd$^{2+}$ and hence lead to a higher CdS particle content. The thermal behavior of this ion-exchangers containing Cd$^{2+}$ or CdS particles was studied.
Starting Page	709
Ending Page	721
Page Count	13
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	63
Issue Number	3
e-ISSN	15728943
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2001-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Physical Chemistry Polymer Sciences Measurement Science, Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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Incorporation of Cadmium Ions and Cadmium Sulfide Particles into Sol-gel Zirconium Phosphate. Synthesis, thermal behavior and X-ray characterization