NDLI: Thermal analysis characterization of isosorbide-containing thermosets : Isosorbide epoxy as BPA replacement for thermosets industry

Content Provider	Springer Nature Link
Author	Feng, Xianhong East, Anthony Hammond, Willis Ophir, Zohar Zhang, Yi Jaffe, Michael
Copyright Year	2012
Abstract	Sugar-based new monomers, polymers, and low molar mass additives have emerged as an exciting topic on green chemistry research, due to the worldwide focus on sustainable material. Isosorbide and its isomers, as “Generally Recognized as Safe” GRAS materials, possess unique stereochemistry and molecular geometry suitable for making cost-effective chemicals and polymers. With growing awareness of bisphenol A (BPA) as a xenoestrogen, isosorbide and its isomers holding the remarkable chemical properties and attractive price can be attached to glycidyl ether to make crosslinkable epoxy resin monomers with similar properties to BPA diglycidyl ether. By adding the hydrophobic functional group into the backbone of isosorbide epoxy or adjusting the amount and type of crosslinker, the mechanical properties and the water uptake ratios (from <1 to >50 wt%) of the isosorbide-derived epoxies could be optimized for different applications. The high water uptake epoxy with controllable biodegradation rate could be used as a drug delivery system or extracellular matrix for biomedical applications while the low water uptake epoxy with strong mechanical properties could be used for can coatings, bone cements, and other industrial additives and adhesives. The chemical structures and properties of the synthesized epoxy monomers and polymers were characterized by DSC, TG, and $^{1}$H NMR.
Starting Page	1267
Ending Page	1275
Page Count	9
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	109
Issue Number	3
e-ISSN	15728943
Language	English
Publisher	Springer Netherlands
Publisher Date	2012-08-17
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	BPA replacement Isosorbide Epoxy Hydrophobic Hydrophilic Bio-based thermoset Measurement Science and Instrumentation Physical Chemistry Analytical Chemistry Inorganic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Thermal characterization of methyltributylammonium-smectites

Thermal degradation of polyethylene containing antioxidant and hydrophilic/hydrophobic silica

Thermal performance, mechanical property and fire behavior of epoxy thermoset based on reactive phosphorus-containing epoxy monomer

Vacuum thermal decomposition of polyethylene containing antioxidant and hydrophilic/hydrophobic silica

Thermal properties of anhydride-cured bio-based epoxy blends

Thermal Analysis Characterization of a Commercial Thermoplastic/Thermoset Adhesive

Study on a novel thermoset nanocomposite form DGEBA–cycloaliphatic diamine and metal nanoparticles : Thermal properties and curing behavior

Polymer blends based on an epoxy-amine thermoset and a thermoplastic : Effect of thermoplastic on cure reaction and thermal stability of the system

Thermal degradation and flame retardancy of epoxy resins containing intumescent flame retardant

Thermal analysis characterization of isosorbide-containing thermosets : Isosorbide epoxy as BPA replacement for thermosets industry

Similar Documents

Thermal characterization of methyltributylammonium-smectites

Thermal degradation of polyethylene containing antioxidant and hydrophilic/hydrophobic silica

Thermal performance, mechanical property and fire behavior of epoxy thermoset based on reactive phosphorus-containing epoxy monomer

Vacuum thermal decomposition of polyethylene containing antioxidant and hydrophilic/hydrophobic silica

Thermal properties of anhydride-cured bio-based epoxy blends

Thermal Analysis Characterization of a Commercial Thermoplastic/Thermoset Adhesive

Study on a novel thermoset nanocomposite form DGEBA–cycloaliphatic diamine and metal nanoparticles : Thermal properties and curing behavior

Polymer blends based on an epoxy-amine thermoset and a thermoplastic : Effect of thermoplastic on cure reaction and thermal stability of the system

Thermal degradation and flame retardancy of epoxy resins containing intumescent flame retardant

Thermal analysis characterization of isosorbide-containing thermosets : Isosorbide epoxy as BPA replacement for thermosets industry