NDLI: Experimental investigation and thermodynamic re-assessment of the Mn

Content Provider	Springer Nature Link
Author	Rong, Maohua Wang, Liya Wang, Jiang Zhu, Chaofan Chen, Taili Rao, Guanghui Zhou, Huaiyin
Copyright Year	2016
Abstract	Fourteen Mn–Nd alloys were investigated experimentally by means of thermal analysis. The temperatures of the invariant reactions and liquidus in the Mn–Nd binary system were determined. Based on the experimental results obtained in the present work as well as the experimental data reported and the previous assessments in the literature, the Mn–Nd binary system was re-assessed thermodynamically using the CALPHAD method. The solution phases, including liquid, α-Mn, β-Mn, γ-Mn, δ-Mn, α-Nd and δ-Nd, are modeled by the substitutional solution model, and their excess Gibbs energies are expressed with the Redlich–Kister polynomial. The intermetallic compounds, Mn$_{2}$Nd, Mn$_{23}$Nd$_{6}$ and Mn$_{17}$Nd$_{2}$, are treated as stoichiometric compounds. A set of self-consistent thermodynamic parameters obtained finally to describe the Gibbs energies of various phases in the Mn–Nd binary system can be used to reproduce well the reported phase equilibria and thermodynamic data.
Starting Page	1437
Ending Page	1445
Page Count	9
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	126
Issue Number	3
e-ISSN	15882926
Language	English
Publisher	Springer Netherlands
Publisher Date	2016-06-24
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Mn–Nd Thermodynamics Thermal analysis CALPHAD Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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