NDLI: Thermal analysis of the interaction of inorganic pigments with p(nBA/MMA) acrylic emulsion before and after UV ageing

Content Provider	Springer Nature Link
Author	Pintus, Valentina Ploeger, Rebecca Chiantore, Oscar Wei, Shuya Schreiner, Manfred
Copyright Year	2012
Abstract	Differential scanning calorimetry (DSC) and thermogravimetry (TG) analyses were used to investigate the influence of inorganic pigments on the photo-oxidative stability of an acrylic emulsion binding medium. For this purpose, three different types of inorganic pigments such as ultramarine blue, cadmium red and hydrated chromium oxide green were selected and mixed with an acrylic emulsion binding medium of poly(n-butyl acrylate/methyl methacrylate). These laboratory mixed paints were analysed before and after UV exposure for different periods of time. In addition, three acrylic commercial paints such as ultramarine blue, cadmium red and chromium oxide green from Liquitex$^{®}$ and Rembrandt$^{®}$ companies were also analysed. The results obtained with both thermal techniques suggested that ultramarine blue has the strongest influence on the photo-oxidative stability of the binding medium. A higher increase of the glass transition temperature T $_{g}$ was observed by DSC analysis on the UV aged binder mixed with ultramarine blue. This result was confirmed by the TG investigations that showed a gradual decrease of the initial temperature of degradation as well as the strongest decrease of the final mass% of the organic compounds. Similar results were measured from the Liquitex$^{®}$ and Rembrandt$^{®}$ blue paints.
Starting Page	33
Ending Page	43
Page Count	11
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	114
Issue Number	1
e-ISSN	15728943
Language	English
Publisher	Springer Netherlands
Publisher Date	2012-12-24
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Acrylic emulsion Inorganic pigments Ultramarine blue UV ageing DSC TG Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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