NDLI: Comparison study on surface depth distribution of chemical species of different nanocomposite Ti

Content Provider	Springer Nature Link
Author	Wang, Luyan Liu, Junkai Meng, Lingqiang Zhong, Congli
Copyright Year	2016
Abstract	Two depths of surface of three kinds of 10 % SiO$_{2}$ Ti–Si binary oxide powder, prepared by three kinds of sol–gel processes and annealed at higher temperature, are comparatively studied by ARXPS, SEM and HRTEM. ARXPS shows that the two depths of surface for all samples enrich in Si about 38.2–63.2 % and are the mixture of TiO$_{ x }$ (x ≤ 2), SiO$_{y}$ (y ≤ 2), Ti–O–Si, adsorbed O-containing species and C-containing species. With increasing depth, the change of Si/Ti ratio closely relates to the original structure formed in sol–gel. The surface contents of SiO$_{2}$ and Ti–O–Si linkages increase in depth for all samples. The surface of silica-supported titania and intimately mixed silica–titania has more sub-valence Ti and Si than that of silica-coated titania, but the surface of silica-coated titania has higher concentration of Ti, O and C than that of the other two. ARXPS and SEM images consistently confirm that the surface of silica-coated titania is a porous structure. HRTEM verifies that nanocrystalline anatase TiO$_{2}$ with many crystal defects has been produced in silica-coated titania.Three nanocomposite silica–titania binary oxide powders with three different structures were synthesized by three different sol–gel processes and analyzed by ARXPS, SEM and HRTEM. As it shows that the surface of silica-coated titania is a porous structure with more O and C, the surfaces of intimately mixed silica–titania and silica-supported titania, respectively, conglomerate and sinter with more suboxide Ti and Si.
Starting Page	142
Ending Page	151
Page Count	10
File Format	PDF
ISSN	09280707
Journal	Journal of Sol-Gel Science and Technology
Volume Number	80
Issue Number	1
e-ISSN	15734846
Language	English
Publisher	Springer US
Publisher Date	2016-04-26
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	TiO$_{2}$ SiO$_{2}$ Surface Comparison Microstructure Depth distribution Ceramics, Glass, Composites, Natural Methods Inorganic Chemistry Optical and Electronic Materials Nanotechnology
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Chemistry Materials Chemistry Biomaterials Condensed Matter Physics Electronic, Optical and Magnetic Materials

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Sol-Gel derived TiO$_{2}$−SiO$_{2}$ fibres

Multifunctional performances of nanocomposite SiO$_{2}$/TiO$_{2}$ doped cationic EBODAC film coated on natural cellulose matrix

Thickness effects in naturally superhydrophilic TiO$_{2}$–SiO$_{2}$ nanocomposite films deposited via a multilayer sol–gel route

Nanoscale composite materials in the system SiO$_{2}$–TiO$_{2}$

Sol–Gel Derived Rh/TiO$_{2}$/SiO$_{2}$ Nanocomposite Membranes

Nanosized TiO$_{2}$ particles decorated on SiO$_{2}$ spheres (TiO$_{2}$/SiO$_{2}$): synthesis and photocatalytic activities

Synthesis of TiO$_{2}$–SiO$_{2}$ aerogel via ambient pressure drying: effects of sol pre-modification on the microstructure and pore characteristics

Erratum to: Nanoscale composite materials in the system SiO$_{2}$–TiO$_{2}$

Tribological properties of multilayer nanostructure TiO$_{2}$ thin film doped by SiO$_{2}$

Comparison study on surface depth distribution of chemical species of different nanocomposite Ti–Si binary oxides

Similar Documents

Sol-Gel derived TiO$_{2}$−SiO$_{2}$ fibres

Multifunctional performances of nanocomposite SiO$_{2}$/TiO$_{2}$ doped cationic EBODAC film coated on natural cellulose matrix

Thickness effects in naturally superhydrophilic TiO$_{2}$–SiO$_{2}$ nanocomposite films deposited via a multilayer sol–gel route

Nanoscale composite materials in the system SiO$_{2}$–TiO$_{2}$

Sol–Gel Derived Rh/TiO$_{2}$/SiO$_{2}$ Nanocomposite Membranes

Nanosized TiO$_{2}$ particles decorated on SiO$_{2}$ spheres (TiO$_{2}$/SiO$_{2}$): synthesis and photocatalytic activities

Synthesis of TiO$_{2}$–SiO$_{2}$ aerogel via ambient pressure drying: effects of sol pre-modification on the microstructure and pore characteristics

Erratum to: Nanoscale composite materials in the system SiO$_{2}$–TiO$_{2}$

Tribological properties of multilayer nanostructure TiO$_{2}$ thin film doped by SiO$_{2}$

Comparison study on surface depth distribution of chemical species of different nanocomposite Ti–Si binary oxides