NDLI: Feasibility of tetracycline, a common antibiotic, as chelating agent for spectrophotometric determination of UO$_{2}$ $^{2+}$ after cloud point extraction

Content Provider	Springer Nature Link
Author	Bağda, Esra Yabaş, Ebru Karakuş, Nihat
Copyright Year	2013
Abstract	A cloud point extraction (CPE) procedure was presented for the preconcentration of UO$_{2}$ $^{2+}$ ion in different water samples. Tetracycline (TC) is the second most widely used antibiotics in the world and is used as chelating agent. To the best of our knowledge, this is the first work that an antibiotic is used as a chelating agent for CPE of UO$_{2}$ $^{2+}$. Besides, the use of TC as complexing agent provides excellent chelating features. TC molecule has large numbers of functional groups (adjacent hydroxyl oxygen atoms and cyclohexanone oxygen atoms, amide groups) which can form stable complex with UO$_{2}$ $^{2+}$. After complexation with TC, UO$_{2}$ $^{2+}$ ions were quantitatively recovered in Triton X-100 after cooling in the ice bath. 3.0 mL of acetate buffer was added to the surfactant-rich phase prior to its analysis by UV–Vis spectrophotometer. The influence of analytical parameters including pH, buffer volume, TC, Triton X-100 concentrations, bath temperature, incubation time were optimized. The effect of the matrix ions on the recovery of UO$_{2}$ $^{2+}$ ions was investigated. The limit of detection was 0.0746 μg mL$^{−1}$ along with enrichment factor of 14.3 with a R.S.D. of 3.6 %. The proposed procedure was applied to the analysis of various environmental water samples. On the other hand, the electronic distribution of TC molecule is investigated with their frontier molecular orbital density distributions.
Starting Page	1813
Ending Page	1820
Page Count	8
File Format	PDF
ISSN	02365731
Journal	Journal of Radioanalytical and Nuclear Chemistry
Volume Number	299
Issue Number	3
e-ISSN	15882780
Language	English
Publisher	Springer Netherlands
Publisher Date	2013-11-13
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Tetracycline Uranium Cloud point extraction Triton X-100 Nuclear Chemistry Physical Chemistry Nuclear Physics, Heavy Ions, Hadrons Diagnostic Radiology Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Spectroscopy Pollution Health, Toxicology and Mutagenesis Radiology, Nuclear Medicine and Imaging Analytical Chemistry Public Health, Environmental and Occupational Health Nuclear Energy and Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Uranium micelle-mediated extraction in acetate medium: factorial design optimization

Micelle-mediated preconcentration using cationic surfactants for the spectrophotometric determination of uranium in aqueous solutions

Spectrophotometric determination of uranium with 5-(2′-carboxyphenyl)azo-8-quinolinol in the non-ionic micellar medium of Triton X-100

Cloud point extraction of $^{99}$Mo with Triton X-114

Uranium determination in water samples by liquid scintillation counting after cloud point extraction

Solvent extraction and spectrophotometric determination of uranium(VI) with pyridine-2-carboxaldehyde 2-hydroxybenzoylhydrazone

Preconcentration of copper by cloud point extraction with 1-(2-pyridylazo)-2-naphthol and determination by neutron activation

Spectrophotometric determination of uranium using chromotrope 2R complexes

Cloud point extraction and spectrophotometric determination of amaranth in food samples using nonionic surfactant Triton X-100 and tetrabutylammonium hydrogen sulfate

Feasibility of tetracycline, a common antibiotic, as chelating agent for spectrophotometric determination of UO$_{2}$ $^{2+}$ after cloud point extraction

Similar Documents

Uranium micelle-mediated extraction in acetate medium: factorial design optimization

Micelle-mediated preconcentration using cationic surfactants for the spectrophotometric determination of uranium in aqueous solutions

Spectrophotometric determination of uranium with 5-(2′-carboxyphenyl)azo-8-quinolinol in the non-ionic micellar medium of Triton X-100

Cloud point extraction of $^{99}$Mo with Triton X-114

Uranium determination in water samples by liquid scintillation counting after cloud point extraction

Solvent extraction and spectrophotometric determination of uranium(VI) with pyridine-2-carboxaldehyde 2-hydroxybenzoylhydrazone

Preconcentration of copper by cloud point extraction with 1-(2-pyridylazo)-2-naphthol and determination by neutron activation

Spectrophotometric determination of uranium using chromotrope 2R complexes

Cloud point extraction and spectrophotometric determination of amaranth in food samples using nonionic surfactant Triton X-100 and tetrabutylammonium hydrogen sulfate

Feasibility of tetracycline, a common antibiotic, as chelating agent for spectrophotometric determination of UO$_{2}$ $^{2+}$ after cloud point extraction