NDLI: Organotin(IV) complexes of polyhydroxyalkyl carboxylic acids and some related ligands

Content Provider	Springer Nature Link
Author	Szorcsik, A. Nagy, L. Gyurcsik, B. Vankó, Gy. Krämer, R. Vértes, A. Yamaguchi, T. Yoshida, K.
Copyright Year	2004
Abstract	A number of dibutyltin(IV) complexes of polyhydroxyalkyl carboxylic acids (O donor atoms) and amino acids (O,N donor atoms) were prepared in the solid state. The binding sites of the ligands were determined by means of FT-IR, Raman and $^{13}$C NMR spectroscopy. Partial quadrupole splitting calculations were utilized to determine the coordination geometry around the Sn(IV) centre by means of Mössbauer measurements. The results showed that in the solid state oligomeric complexes are formed, with the -COO$^{-}$ groups as bridges between the organometallic cations. The {Sn} atoms are mostly in trigonal bipyramidal surroundings. The Sn-O and Sn-C bond distances were determined by EXAFS measurements to be 207-234 and 295 pm, respectively. Evaluation of the pH-metric and NMR titration curves in Me$_{2}$Sn(IV)-D-gluconic acid system revealed that the equilibria in aqueous solution are fairly complicated. In acidic solution, the formation of 1 : 1 and 1 : 2 -COO$^{-}$ coordinated species predominate, but deprotonation of the alcoholic -OH groups also starts at very low pH. In the pH range 5-9, NMR provides experimental evidence of ligand-exchange reactions without pH-metrically detectable proton release. In alkaline solution, further deprotonation processes occur, resulting in either alkoxo or mixed hydroxo complexes. The carboxylate coordination is expected for the amino acid ligands but the shift of the νN-H stretching vibrations in the FT-IR spectra demonstrated that the ammine group also binds to the metal ion in the solid Bu$_{2}$Sn(IV)complexes.
Starting Page	459
Ending Page	469
Page Count	11
File Format	PDF
ISSN	02365731
Journal	Journal of Radioanalytical and Nuclear Chemistry
Volume Number	260
Issue Number	3
e-ISSN	15882780
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2004-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Physical Chemistry Diagnostic Radiology Nuclear Physics, Heavy Ions, Hadrons Nuclear Chemistry
Content Type	Text
Resource Type	Article
Subject	Spectroscopy Pollution Health, Toxicology and Mutagenesis Radiology, Nuclear Medicine and Imaging Analytical Chemistry Public Health, Environmental and Occupational Health Nuclear Energy and Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Preparation and structural studies of organotin(IV) complexes formed with organic carboxylic acids

Preparation and structural studies of organotin(IV) complexes formed with organic carboxylic acids

Structural studies on organotin(IV) complexes formed with ligands containing {S,N,O} donor atoms

Organotin(IV) coordination by oxime analogues of amino acids and peptides

Preparation and structural studies on organotin(IV) complexes with flavonoids

Preparation and XAFS studies of organotin(IV) complexes with adenosine and related compounds and calf thymus DNA

Mössbauer magnetization and nuclear magnetic resonance measurements on some iridium(I) complexes with fullerene ligands

Effects of side-chains ofN-acetylamino acids on the structures of their triphenyltin(IV) complexes

Preparation and spectroscopic studies of diorganotin(IV) complexes with adenosine and related compounds

Organotin(IV) complexes of polyhydroxyalkyl carboxylic acids and some related ligands

Similar Documents

Preparation and structural studies of organotin(IV) complexes formed with organic carboxylic acids

Preparation and structural studies of organotin(IV) complexes formed with organic carboxylic acids

Structural studies on organotin(IV) complexes formed with ligands containing {S,N,O} donor atoms

Organotin(IV) coordination by oxime analogues of amino acids and peptides

Preparation and structural studies on organotin(IV) complexes with flavonoids

Preparation and XAFS studies of organotin(IV) complexes with adenosine and related compounds and calf thymus DNA

Mössbauer magnetization and nuclear magnetic resonance measurements on some iridium(I) complexes with fullerene ligands

Effects of side-chains ofN-acetylamino acids on the structures of their triphenyltin(IV) complexes

Preparation and spectroscopic studies of diorganotin(IV) complexes with adenosine and related compounds

Organotin(IV) complexes of polyhydroxyalkyl carboxylic acids and some related ligands