NDLI: The Influence of an Acid-base-equilibrium on the Adsorption Behaviour of a Weak Polyampholyte

Content Provider	Springer Nature Link
Author	Mahltig, Boris Jérôme, Robert Stamm, Manfred
Copyright Year	2003
Abstract	A weak diblock polyampholyte PMAA-b-PDMAEMA, poly(methacrylic acid)-block-poly((dimethylamino)ethyl methacrylate), was investigated as a model system for the influence of an acid-base-equilibrium of a phthalic acid buffer system on the polyelectrolyte adsorption behaviour. The adsorption of polyampholyte from aqueous solution onto silicon surfaces is known to be strongly influenced by the parameters of the polymer solution and the properties of the polyampholyte itself like block ratio or molecular weight. In the case of the investigated polyampholytes, the main parameter with the most significant influence on the adsorption is the pH. The big influence of pH on adsorption results from the charges of the polymer chains and the substrate, which are determined by the pH. Therefore, it should be useful to investigate the influence of a buffer system on the polyampholyte adsorption. On the one hand the buffer system enables to determine the pH of the aqueous polyampholyte solution more precisely. On the other hand the concentrations of different phthalic species like the phthalic acid, the hydrogen phthalate and the phthalate are strongly influenced by pH. These different species were observed to have a strong influence on the adsorption behaviour of the polyampholyte, so the adsorption as function of pH was observed to be also determined by the acid-base-equilibrium of the buffer system. The adsorbed amount of polyampholyte dried after the adsorption process was determined using ellipsometry, while the surface topography of these adsorbed layers were characterized by atomic force microscopy (AFM).
Starting Page	219
Ending Page	223
Page Count	5
File Format	PDF
ISSN	10229760
Journal	Journal of Polymer Research
Volume Number	10
Issue Number	4
e-ISSN	15728935
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2003-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Polymer Sciences Industrial Chemistry/Chemical Engineering Characterization and Evaluation Materials
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Materials Chemistry Polymers and Plastics

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