NDLI: Competitive Self and Induced Aggregation of Calix[4]arene Ethers and Their Interaction with Pinacyanol Chloride and Methylene Blue in Nonaqueous Media

Content Provider	Springer Nature Link
Author	Pandey, Shubha Kar, Jyotsna R. Azam, Amir Pandey, Siddharth Chawla, H. M.
Copyright Year	2010
Abstract	Long chain calix[4]arene ethers have been examined for aggregation in nonaqueous solvents by using UV-vis molecular absorbance spectroscopy. It has been observed that tetraalkylated (alkyl = hexadecyl and octadecyl, respectively) calix[4]arene ethers tend to aggregate in chloroform and tetrahydrofuran, possibly via π–π stacking interactions of the phenyl moieties, and the aggregation process appears to be facilitated by the alkyl chains. The analogous dialkylated compounds do not show any self-aggregation, plausibly due to strong hydrogen bonding between the –OH and the –O– of calix aryl ether which seems to disrupt the aggregation process. Addition of the anionic surfactant sodium dodecylsulfate (SDS) appears to hinder the aggregation process in nonpolar chloroform but the same surfactant facilitates aggregation in the polar tetrahydrofuran. The cationic surfactant (cetyltrimethyl ammonium bromide) and the nonionic surfactant (Brij-35) have no effect on this aggregation process. Unexpectedly, SDS induces aggregation of dialkylated calix[4]arene ethers in chloroform. It has been observed that the aggregated form of the tetraalkylated calix[4]arene ethers tend to increase the dimerization efficiency of cationic dyes (pinacyanol chloride and methylene blue) in chloroform.
Starting Page	107
Ending Page	120
Page Count	14
File Format	PDF
ISSN	00959782
Journal	Journal of Solution Chemistry
Volume Number	39
Issue Number	1
e-ISSN	15728927
Language	English
Publisher	Springer US
Publisher Date	2010-01-05
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Condensed Matter Physics Inorganic Chemistry Oceanography Geochemistry Industrial Chemistry/Chemical Engineering Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

UV/Vis Spectral Study of the Self-aggregation of Pinacyanol Chloride in Ethanol–Water Solutions

Bis(crown-6)calix[4]arene/Cs$^{+}$ Coordination Chemistry in NPME Solution

Decoration of MWCNTs with CoFe$_{2}$O$_{4}$ Nanoparticles for Methylene Blue Dye Adsorption

A Rational Approach Towards Determination of Optical Ionicity and Non-covalent Interactions in Fullerene-Calix[4]arene Host-Guest Complexes

Intermolecular Complexation Between p-Sulfonated Calix[4,6,8]arene Sodium and Neutral Red

Interaction of Coumarin 7 and Coumarin 314 with C-hexylpyrogallol[4]arene

Thermodynamics of Complexation of Alkali Metal Cations by a Lower-Rim Calix[4]arene Amino Acid Derivative

Complexation of p-Sulphonato-calix[6]arene by Glycine, Glycyl-glycine, and Glycyl-glycyl-glycine in Aqueous Solution

Kinetic Study of the Reaction of Leuco Methylene Blue with 2,6-Dimethyl-p-benzoquinone in a Reverse Micellar System

Competitive Self and Induced Aggregation of Calix[4]arene Ethers and Their Interaction with Pinacyanol Chloride and Methylene Blue in Nonaqueous Media

Similar Documents

UV/Vis Spectral Study of the Self-aggregation of Pinacyanol Chloride in Ethanol–Water Solutions

Bis(crown-6)calix[4]arene/Cs$^{+}$ Coordination Chemistry in NPME Solution

Decoration of MWCNTs with CoFe$_{2}$O$_{4}$ Nanoparticles for Methylene Blue Dye Adsorption

A Rational Approach Towards Determination of Optical Ionicity and Non-covalent Interactions in Fullerene-Calix[4]arene Host-Guest Complexes

Intermolecular Complexation Between p-Sulfonated Calix[4,6,8]arene Sodium and Neutral Red

Interaction of Coumarin 7 and Coumarin 314 with C-hexylpyrogallol[4]arene

Thermodynamics of Complexation of Alkali Metal Cations by a Lower-Rim Calix[4]arene Amino Acid Derivative

Complexation of p-Sulphonato-calix[6]arene by Glycine, Glycyl-glycine, and Glycyl-glycyl-glycine in Aqueous Solution

Kinetic Study of the Reaction of Leuco Methylene Blue with 2,6-Dimethyl-p-benzoquinone in a Reverse Micellar System

Competitive Self and Induced Aggregation of Calix[4]arene Ethers and Their Interaction with Pinacyanol Chloride and Methylene Blue in Nonaqueous Media