NDLI: In Situ Identification of Carbonate-Containing Green Rust on Iron Electrodes in Solutions Simulating Groundwater

Content Provider	Springer Nature Link
Author	Bonin, P. M. L. Odziemkowski, M. S. Reardon, E. J. Gillham, R. W.
Copyright Year	2000
Abstract	Open-circuit potential-time and spectral measurements were performed on ironelectrodes in aqueous solutions containing calcium carbonate to simulateground-water, to which an amount of carbon tetrachloride was added. In the case of apreoxidized iron electrode, the injection of the chlorinated aliphatic hydrocarbonresulted in the formation of carbonate-containing green rust. In situ identification,performed by Raman spectroscopy, was based on bands at ca. 433, 509, and1053 cm$^{−1}$, which were assigned, respectively, to the Fe$^{2+}$—OH stretching modeof green rust, the Fe$^{3+}$—OH stretching mode of green rust, and the stretchingvibrations of carbonate ions in the interlayer regions of the green rust. Theassignment of the Fe$^{2+}$—OH and Fe$^{3+}$−OH stretching mode bands was confirmedby parallel experiments using D$_{2}$O solution. The results of the open-circuitpotential-time experiments are in good agreement with literature thermodynamic datafor iron in carbonate-containing aqueous solutions.
Starting Page	1061
Ending Page	1074
Page Count	14
File Format	PDF
ISSN	00959782
Journal	Journal of Solution Chemistry
Volume Number	29
Issue Number	10
e-ISSN	15728927
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2000-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Physical Chemistry Industrial Chemistry/Chemical Engineering Condensed Matter
Content Type	Text
Resource Type	Article
Subject	Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry

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