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| Content Provider | Springer Nature Link |
|---|---|
| Author | Medina Gonzalez, Y. Caro, P. Thiebaud Roux, S. Lacaze Dufaure, C. |
| Copyright Year | 2007 |
| Abstract | The C8 to C18 fatty acid methyl esters (FAME) have been compared as solvents for two epoxy resin pre-polymers, bisphenol A diglycidyl ether (DGEBA) and triglycidyl p-aminophenol ether (TGPA). It was found that the solubilization limits vary according to the ester and that methyl caprylate is the best solvent of both resins. To explain these solubility performances, physical and chemical properties of FAME were studied, such as the Hansen parameters, viscosity, binary diffusion coefficient and vaporization enthalpy. Determination of the physicochemical parameters of FAME was carried out by laboratory experimentations and by calculation from bibliographic data. The Hansen parameters of FAME and epoxy resins pre-polymers were theoretically and experimentally determined. The FAME chain length showed a long dependence on the binary diffusion parameters and kinematic viscosity, which are mass and momentum transport properties. Moreover, the vaporization enthalpy of these compounds was directly correlated with the solubilization limits. |
| Starting Page | 437 |
| Ending Page | 446 |
| Page Count | 10 |
| File Format | |
| ISSN | 00959782 |
| Journal | Journal of Solution Chemistry |
| Volume Number | 36 |
| Issue Number | 4 |
| e-ISSN | 15728927 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2007-03-31 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Biosolvents, FAME Epoxy Resins Surface cleaning Physicochemical parameters Hansen parameters Dipole moment Condensed Matter Inorganic Chemistry Oceanography Geochemistry Industrial Chemistry/Chemical Engineering Physical Chemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry |
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