NDLI: Partial Molar Volumes and Refractions of Cobalt(III) Complexes, Part 2: Homologous Series of Nitrilopentaamminecobalt(III) Complexes

Content Provider	Springer Nature Link
Author	Fucaloro, Anthony Pinnell, Robert Zanella, Andrew Conrad, Karen Pu, Yan
Copyright Year	2005
Abstract	Both the partial molar volumes (V° $_{2m }$ refractions (R° $_{2m }$) of the solutes at infinite dilution have been determined at 20 °C for a series of six octahedral N$_{6}$-coordinated cobalt(III) species featuring five coordinated ammonia ligands along with a sixth N-coordinated organonitrile of increasing ligand size (from acetonitrile to sebaconitrile). The experimental values for V° $_{2m }$ are consistent with the relative sizes of the ligands but show larger values than those generated by computer modeling as the size of the cation increases, presumably due to the void space of the cation which increases with the size of the nitrile ligand.
Starting Page	1245
Ending Page	1254
Page Count	10
File Format	PDF
ISSN	00959782
Journal	Journal of Solution Chemistry
Volume Number	35
Issue Number	9
e-ISSN	15728927
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2006-09-27
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Nitrile ligands Cobalt(III) complexes Molar volume Partial molar volume Molar refraction Condensed Matter Inorganic Chemistry Oceanography Geochemistry Industrial Chemistry/Chemical Engineering Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Biochemistry Molecular Biology Biophysics Physical and Theoretical Chemistry

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Partial Molar Volumes and Refractions of Cobalt(III) Complexes, Part 2: Homologous Series of Nitrilopentaamminecobalt(III) Complexes