NDLI: Crystal structure of a two-dimensional Co(II) coordination polymer: [Co(μ-PP)$_{2}$(SCN)$_{2}$]$_{ n }$ [PP = 2-(pyridine-3-yloxy)pyrazine]

Content Provider	Springer Nature Link
Author	Li, H. Zhao, H. Y. Zhang, S. G. Shi, J. M.
Copyright Year	2009
Abstract	Solvothermal reaction (water/methanol) of cobalt perchlorate hexahydrate, sodium thiocyanate and 2-(pyridine-3-yloxy)pyrazine (PP) resulted in the formation of a two-dimensional coordination polymer [Co(μ-PP)$_{2}$(SCN)$_{2}$]$_{ n }$. The solid complex has been characterized by elemental analysis and IR spectroscopy; its crystal structure was determined by X-ray crystallography. The complex crystallizes in the monoclinic system, space group P2$_{1}$/n, a = 7.4643(19) Å, b = 9.237(2) Å, c = 15.540(4) Å, β = 94.995(5)°, V = 1067.4(5) Å$^{3}$, Z = 1. In the crystal structure each 2-(pyridine-3-yloxy)pyrazine molecule acts as a bidentate bridging ligand coordinating to two adjacent Co(II) ions with Co...Co separation of 9.5176(18) Å to yield a two-dimensional sheet structure in the plane (−1 0 1).
Starting Page	373
Ending Page	377
Page Count	5
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	50
Issue Number	2
e-ISSN	15738779
Language	English
Publisher	Springer US
Publisher Date	2009-05-15
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	crystal structure cobalt(II) complex 2D polymer layered structure Solid State Physics and Spectroscopy Atomic and Molecular Structure and Spectra Atoms, Molecules, Clusters and Plasmas Physical Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Physical and Theoretical Chemistry Inorganic Chemistry

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