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| Content Provider | Springer Nature Link | 
|---|---|
| Author | Koudryavtsev, A. B. Linert, W. | 
| Copyright Year | 2009 | 
| Abstract | The theoretical models of spin crossover (equilibrium between the high- and low-spin isomers of transition metal complexes) are compared. The models yield similar descriptions of the one-step spin crossover, but different descriptions of the two-step transition curves because of different approaches to the calculation of molecular interactions. The parameters of the Ising-like Hamiltonian reflect the lattice response to the distribution of molecules, and the parameters of the free energy functional reflect the molecular interactions, due to which the sharpness of transition can be correlated with the molecular properties. | 
| Starting Page | 1181 | 
| Ending Page | 1185 | 
| Page Count | 5 | 
| File Format | |
| ISSN | 00224766 | 
| Journal | Journal of Structural Chemistry | 
| Volume Number | 50 | 
| Issue Number | 6 | 
| e-ISSN | 15738779 | 
| Language | English | 
| Publisher | Springer US | 
| Publisher Date | 2010-02-04 | 
| Publisher Place | Boston | 
| Access Restriction | One Nation One Subscription (ONOS) | 
| Subject Keyword | spin crossover Ising-like potential model molecular statistical model Solid State Physics Atomic/Molecular Structure and Spectra Atomic, Molecular, Optical and Plasma Physics Physical Chemistry Inorganic Chemistry | 
| Content Type | Text | 
| Resource Type | Article | 
| Subject | Materials Chemistry Physical and Theoretical Chemistry Inorganic Chemistry | 
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