NDLI: Synthesis and Molecular and Crystal Structure of K$_{4.5}${[Mo$_{3}$(μ$_{3}$-Te)(μ$_{2}$-Te$_{2}$)$_{3}$(CN)$_{6}$]I}I$_{1.5}$·3H$_{2}$O and Cs$_{3}${[Mo$_{3}$(μ$_{3}$-Te)(μ$_{2}$-Te$_{2}$)$_{3}$(CN)$_{6}$]I}·2H$

Content Provider	Springer Nature Link
Author	Pervukhina, N. V. Podberezskaya, N. V. Kalinina, I. V. Fedin, V. P.
Copyright Year	2000
Abstract	Crystal structures of two new compounds containing trigonal tellurium-bridged cluster fragments [Mo$_{3}$(μ$_{3}$-Te)(μ$_{2}$-Te$_{2}$)$_{3}$]$^{4+}$ were investigated. Crystal data for K$_{4.5}${[Mo$_{3}$(μ$_{3}$-Te)(μ$_{2}$-Te$_{2}$)$_{3}$(CN)$_{6}$]I}I$_{1.5}$·3H$_{2}$O: space group $$P\bar 3c1$$ , Z = 4, a = 13.280(1), c = 23.800(3) Å, V = 3635.0(6) Å$^{3}$, d $_{ calc }$ = 3.432 g/cm$^{3}$, R $_{ 1 }$ = 0.0335, wR2 = 0.0912 for 1378 I $_{ hkl }$ > 2 σ$_{I}$ from 3545 measured I $_{ hkl }$; for Cs$_{3}${[Mo$_{3}$(μ$_{3}$-Te)(μ$_{2}$-Te$_{2}$)$_{3}$(CN)$_{6}$]I}·2H$_{2}$O: space group P2 $_{ 1 }$ /n, Z = 2, a= 9.650(2) , b = 22.297(5), c = 27.446(7) Å, β = 94.10(2)°, V = 5890(2) Å$^{3}$, d $_{ calc }$ = 4.273 g/cm $^{3}$, R $_{ 1 }$ = 0.0384, wR $_{ 2 }$ = 0.0744 for 957 I $_{ hkl }$ > 2 σ$_{I}$ from 3758 measured I $_{ hkl }$ (Enraf-Nonius CAD-4 diffractometer, λMoK $_{α}$, graphite monochromator). In both compounds, ionic pairs {[Mo$_{3}$Te$_{7}$(CN)$_{6}$]I}$^{3–}$ with Te$_{ax}$...I$^{–}$ distances of 3.358-3.676 Å are formed. In the potassium salt, the {[Mo$_{3}$Te$_{7}$(CN)$_{6}$]I}$^{3–}$ anion pairs are linked by the additional Te$_{eq}$⋯I$^{–}$ short contacts of 3.460 Å into two-dimensional corrugated layers perpendicular to the c axis of the unit cell. The structure of the cesium salt is ionic with interstitial H$_{2}$O molecules and double-layer closest packing of anions.
Starting Page	843
Ending Page	850
Page Count	8
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	41
Issue Number	5
e-ISSN	15738779
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2000-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Physical Chemistry Atoms, Molecules, Clusters and Plasmas
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Physical and Theoretical Chemistry Inorganic Chemistry

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