NDLI: To the Understanding of the Structural Sensitivity of the Temperature Coefficient of Internal Pressure

Content Provider	Springer Nature Link
Author	Kartsev, V. N.
Copyright Year	2004
Abstract	The previously found empirical relationships between the temperature coefficient of internal pressure, on the one hand, and the structure and its evolution in liquids due to variations of temperature and concentration, on the other, are interpreted in terms of the peculiarities of intermolecular interactions. Analysis has revealed that the curves of the temperature dependences of internal pressure P $_{i}$(T) of associated liquids are directed upward by their concavity; they have a minimum and asymptotically tend toward P $_{i}$ = 0 at T→∞. The curves P $_{i}$(T) of weakly associated liquids are directed downward by their concavity and have no extrema, but asymptotically tend to zero at T→∞.
Starting Page	832
Ending Page	837
Page Count	6
File Format	PDF
ISSN	00224766
Journal	Journal of Structural Chemistry
Volume Number	45
Issue Number	5
e-ISSN	15738779
Language	English
Publisher	Kluwer Academic Publishers-Consultants Bureau
Publisher Date	2004-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	structure intermolecular interactions internal pressure Inorganic Chemistry Physical Chemistry Atoms, Molecules, Clusters and Plasmas Atomic and Molecular Structure and Spectra Solid State Physics and Spectroscopy
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Physical and Theoretical Chemistry Inorganic Chemistry

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To the Understanding of the Structural Sensitivity of the Temperature Coefficient of Internal Pressure