NDLI: Ion exchange kinetics and thermodynamics of hydrosodalite, a narrow pore zeolite

Content Provider	Springer Nature Link
Author	Aprea, P. Caputo, D. Gargiulo, N. Gennaro, B. Iucola, F. Liguori, B. Colella, C.
Copyright Year	2014
Abstract	The ion-exchange properties of a synthetic hydrosodalite (Na-hS) have been investigated by kinetic and thermodynamic analysis of exchange reactions of the original sodium form for lithium, potassium and calcium forms. Kinetic curves, modelled by a Langmuir-type equation, revealed that exchange rate for lithium and for potassium are of the same order, whereas they are two order faster than for calcium. Thermodynamic analysis of the cation exchange isotherms pointed out that sodalite is selective for sodium over the other three cationic forms examined, which is consistent with the preference exhibited by the sodalite type for sodium environments, either in natural or in laboratory crystallization. Na/Li and Na/Ca exchanges are incomplete, whereas unexpectedly Na/K exchange turns out to be complete, even though K$^{+}$ dimension exceeds the width of the access window to sodalite cages. The obtained results have been discussed in terms of Eisenman–Sherry theory, pointing out agreements and discrepancies.
Starting Page	643
Ending Page	651
Page Count	9
File Format	PDF
ISSN	13802224
Journal	Journal of Porous Materials
Volume Number	21
Issue Number	5
e-ISSN	15734854
Language	English
Publisher	Springer US
Publisher Date	2014-04-27
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Hydrosodalite Hydroxysodalite Cation exchange kinetics Cation exchange isotherms Catalysis Characterization and Evaluation of Materials Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Mechanics of Materials Materials Science Mechanical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Entrapping noxious cations in ceramic matrices

Complete Li$^{+}$ exchange into zeolite X (FAU, Si/Al = 1.09) from undried methanol solution

Isotherms and thermodynamics studies for binary adsorption of methane and ethane on 4A molecular sieve zeolite

Preparation of CPB-modified FAU zeolite for the removal of tannery wastewater contaminants

Single-crystal structures of Zn$^{2+}$-exchanged zeolite A: dependence on Zn$^{2+}$ concentration of aqueous solution during exchange

Structural characteristics of modified natural zeolite

Mesoporous Material from Zeolite

Zeolite beta monoliths with hierarchical porosity by the transformation of bimodal pore silica gel

Effect of anion species from Ca-sources on framework type of Na–Ca zeolites prepared at 80°C

Ion exchange kinetics and thermodynamics of hydrosodalite, a narrow pore zeolite

Similar Documents

Entrapping noxious cations in ceramic matrices

Complete Li$^{+}$ exchange into zeolite X (FAU, Si/Al = 1.09) from undried methanol solution

Isotherms and thermodynamics studies for binary adsorption of methane and ethane on 4A molecular sieve zeolite

Preparation of CPB-modified FAU zeolite for the removal of tannery wastewater contaminants

Single-crystal structures of Zn$^{2+}$-exchanged zeolite A: dependence on Zn$^{2+}$ concentration of aqueous solution during exchange

Structural characteristics of modified natural zeolite

Mesoporous Material from Zeolite

Zeolite beta monoliths with hierarchical porosity by the transformation of bimodal pore silica gel

Effect of anion species from Ca-sources on framework type of Na–Ca zeolites prepared at 80°C

Ion exchange kinetics and thermodynamics of hydrosodalite, a narrow pore zeolite