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| Content Provider | Springer Nature Link |
|---|---|
| Author | Way, Cameron Wu, Dong Yang Cram, Darren Dean, Katherine Palombo, Enzo |
| Copyright Year | 2012 |
| Abstract | Polylactic acid (PLA) composites comprising up to 25 wt% cotton linter (CL) or up to 50 % maple wood fibre (WF) were prepared by compounding and injection moulding. A reduction of crystallinity in the PLA matrix was observed as a result of the thermal processing method. These PLACL and PLAWF composites provided excellent improvements in both stiffness (with increases in tensile and flexural modulus) and toughness (increases in notched impact strength) properties over the neat PLA resin, while the tensile and flexural strengths of the composites were generally unchanged, while the strain at break values were reduced in comparison to the neat PLA. DMA results indicated incorporating these fibres caused the mechanical loss factor (tan δ) to decrease, suggesting better damping capabilities were achieved with the composites. SEM analysis of the impact fractured surfaces of the PLACL composites showed debonding-cavitation at the matrix-fibre interface while the PLAWF composites showed good wetting along its matrix-fibre interface. The composting of these composites up to 90 days showed that the degradation onset time was increased when increasing the fibre loadings, but the maximum degree of degradation and the maximum daily rates of degradation were decreased compared to neat PLA. On a weight basis of fibre loading, the PLACL composites had a quicker onset of biodegradation, a higher maximum daily rate of biodegradation and, overall, a higher degree of biodegradation at 90 days than the PLAWF composites, possibly due to the quicker thermal hydrolysis observed in the PLA matrix of the PLACL composites during processing and composting. |
| Starting Page | 54 |
| Ending Page | 70 |
| Page Count | 17 |
| File Format | |
| ISSN | 15662543 |
| Journal | Journal of Polymers and the Environment |
| Volume Number | 21 |
| Issue Number | 1 |
| e-ISSN | 15728900 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2012-04-21 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Cotton linters Maple fibres Polylactic acid (PLA) Thermomechanical properties Scanning electron microscopy Biodegradation Composting Polymer Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Environmental Engineering Polymers and Plastics |
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