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| Content Provider | Springer Nature Link |
|---|---|
| Author | Rutkowska, Maria Krasowska, Katarzyna Heimowska, Aleksandra Adamus, Grażyna Sobota, Michał Musioł, Marta Janeczek, Henryk Sikorska, Wanda Krzan, Andrej Žagar, Ema Kowalczuk, Marek |
| Copyright Year | 2008 |
| Abstract | Degradation of atactic poly[(R,S)-3-hydroxybutyrate] (a-PHB) binary blends with natural poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV, 12 mol% of 3HV units), has been investigated and compared with plain PHBV in the compost containing activated sludge and under marine exposure conditions in the dynamic water of the Baltic Sea. Characteristic parameters of compost and the Baltic Sea water were monitored during the incubation period (6 weeks) and their influence on the degree of biodegradation is discussed. After specified degradation times of the experiments the weight loss of the samples, surface changes, changes in molecular weight and polydispersity as well as changes of the composition and thermo-mechanical properties of the blends have been evaluated. Macroscopic observations of the samples were accompanied by investigations using optical microscopy, size-exclusion chromatography (SEC), nuclear magnetic resonance (NMR), differential scanning calorimetry (DSC) and tensile testing. The degree of degradation of blends of a-PHB with PHBV depends on the blend composition and environmental conditions. In both environments studied the weight loss of plain PHBV was more significant than changes the molecular weight. In both environments only enzymatic degradation of the blends, which proceeds via surface erosion mechanisms, was observed during the incubation period. |
| Starting Page | 183 |
| Ending Page | 191 |
| Page Count | 9 |
| File Format | |
| ISSN | 15662543 |
| Journal | Journal of Polymers and the Environment |
| Volume Number | 16 |
| Issue Number | 3 |
| e-ISSN | 15728900 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2008-05-03 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Atactic poly[(R,S)-3-hydroxybutyrate] Natural poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Biodegradation Compost with activated sludge Baltic Sea water Polymer Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Environmental Engineering Polymers and Plastics |
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