NDLI: Local Atomic and Electronic Structure with Magnetism of La$_{0.7}$Ca$_{0.3}$Mn$_{1−x }$Cu$_{ x }$O$

Content Provider	Springer Nature Link
Author	Zhang, Hongguang Shi, Jiangjian Li, Yongtao Liu, Hao Dong, Xueguang Chen, Kai Hou, Qingteng Huang, Yongchao Ge, Xiaopeng Zhao, Liang Lu, Zixing Li, Qi
Copyright Year	2012
Abstract	Local atomic and electronic structure with magnetic properties, especially Griffiths phase, of polycrystalline samples La$_{0.7}$Ca$_{0.3}$Mn$_{1−x }$Cu$_{ x }$O$_{3}$ (x=0, 0.03, 0.06, 0.1) have been studied. The X-ray absorption spectra (XAS) of Cu 2p core level prove that the valence state of Cu ions exhibits trivalent state when doping content x≤0.06 and divalent Cu$^{2+}$ ions begin to show for x=0.1. For the valence states of Mn ions, the X-ray photoelectron spectroscopy data show that they are in mixed states of Mn$^{3+}$ and Mn$^{4+}$, and a shift to lower binding energy is observed, which is not attributed to the variation of valence states of Mn ions but the change of crystallographic surroundings, because there is no obvious change detected by X-ray absorption fine structure spectroscopy (XAFS). The Debye-Waller factor (σ $^{2}$) of x=0.1 sample is only slightly larger compared to x=0, which may be the origin of enhancement of Griffiths phase observed in the inverse-susceptibility as a function of temperature (H/M∼T). The H/M∼T curves of Cu doped samples indicate coexistence of FM, AFM and PM phase above Curie temperature T $_{ C }$, which may be related to the strong hybridization of O 2p and Mn 3d reflected by O 1s XAS spectra.
Starting Page	77
Ending Page	89
Page Count	13
File Format	PDF
ISSN	00222291
Journal	Journal of Low Temperature Physics
Volume Number	169
Issue Number	1-2
e-ISSN	15737357
Language	English
Publisher	Springer US
Publisher Date	2012-06-12
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Quenched disorder Griffiths phase X-ray absorption fine structure (XAFS) X-ray photoelectron spectroscopy (XPS) Ferromagnetism Magnetism, Magnetic Materials Characterization and Evaluation of Materials Condensed Matter Physics
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Condensed Matter Physics Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Photoemission Line shape Study on La$_{0.7}$Sr$_{0.3}$Mn$_{1-\delta}$Al$_\delta$O$_{3}$ ($\delta$ = 0, 0.03, 0.06)

Magnetism in La$_{0.7}$Sr$_{0.3}$Mn$_{1-x}$Co$_x$O$_3$ ($0 \leq x \leq 1$)

Griffiths Phase and Disorder in Perovskite Manganite Oxides La$_{1−x }$Ca$_{ x }$MnO$_{3}$ and La$_{0.7}$Sr$_{0.3}$MnO$_{3}$

Disappearance of Griffiths Phase in Polycrystalline Sample La$_{0.75}$Ca$_{0.15}$MnO$_{3−Δ}$ with Controlling Oxygen Vacancy

Appearance of Griffiths Phase in La$_{0.7−x }$Pr$_{ x }$Ba$_{0.3}$MnO$_{3}$ (0 ≤x≤ 0.2)

Orientation-dependent X-ray Absorption Fine Structure (XAFS) of the Bi-St=Ca-Cu-0 System (1992)

Griffiths Phase and Reduced Magnetization of La$_{0.5}$Ca$_{0.5}$MnO$_{3}$ with Different Annealing Temperature

Orientation-dependent X-ray Absorption Fine Structure (XAFS) of the Bi-St=Ca-Cu-0 System

Variation of the Ru moment in the Ca(0.3)Sr(0.7)Ru(1-x)Mn(x)O3 system.

Local Atomic and Electronic Structure with Magnetism of La$_{0.7}$Ca$_{0.3}$Mn$_{1−x }$Cu$_{ x }$O$_{3}$ (x=0, 0.03, 0.06, 0.1)

Similar Documents

Photoemission Line shape Study on La$_{0.7}$Sr$_{0.3}$Mn$_{1-\delta}$Al$_\delta$O$_{3}$ ($\delta$ = 0, 0.03, 0.06)

Magnetism in La$_{0.7}$Sr$_{0.3}$Mn$_{1-x}$Co$_x$O$_3$ ($0 \leq x \leq 1$)

Griffiths Phase and Disorder in Perovskite Manganite Oxides La$_{1−x }$Ca$_{ x }$MnO$_{3}$ and La$_{0.7}$Sr$_{0.3}$MnO$_{3}$

Disappearance of Griffiths Phase in Polycrystalline Sample La$_{0.75}$Ca$_{0.15}$MnO$_{3−Δ}$ with Controlling Oxygen Vacancy

Appearance of Griffiths Phase in La$_{0.7−x }$Pr$_{ x }$Ba$_{0.3}$MnO$_{3}$ (0 ≤x≤ 0.2)

Orientation-dependent X-ray Absorption Fine Structure (XAFS) of the Bi-St=Ca-Cu-0 System (1992)

Griffiths Phase and Reduced Magnetization of La$_{0.5}$Ca$_{0.5}$MnO$_{3}$ with Different Annealing Temperature

Orientation-dependent X-ray Absorption Fine Structure (XAFS) of the Bi-St=Ca-Cu-0 System

Variation of the Ru moment in the Ca(0.3)Sr(0.7)Ru(1-x)Mn(x)O3 system.

Local Atomic and Electronic Structure with Magnetism of La$_{0.7}$Ca$_{0.3}$Mn$_{1−x }$Cu$_{ x }$O$_{3}$ (x=0, 0.03, 0.06, 0.1)