NDLI: Two electrically different molecular conductors based on unsymmetrical Au(III)-dithiolene complexes with similar crystal structures

Content Provider	Springer Nature Link
Author	Kubo, Kazuya Nakao, Akiko Ishii, Yasuyuki Tamura, Masafumi Kato, Reizo Matsubayashi, Gen etsu
Copyright Year	2006
Abstract	The cation radical salt based on unsymmetrical metal-dithiolene complexes [Au(ppy)(C$_{8}$H$_{4}$S$_{8}$)]$_{2}$[PF$_{6}$] (1) is a semiconductor with small activation energy under ambient pressure, and shows metallic behavior under high pressure. On the other hand, [Au(ppy)(C$_{8}$H$_{4}$S$_{6}$O$_{2}$)]$_{2}$[BF$_{4}$] (2) is an insulator in spite of the structural similarity. Effective conduction pathways through the S···S contacts were found in the crystal structure of1. However, the crystal of2 contains no such conduction pathways. Comparison of the energy band structures of1 and2 suggests that even a subtle difference in cation arrangements makes a remarkable difference between the electrical properties of1 and2.
Starting Page	413
Ending Page	416
Page Count	4
File Format	PDF
ISSN	00222291
Journal	Journal of Low Temperature Physics
Volume Number	142
Issue Number	3-4
e-ISSN	15737357
Language	English
Publisher	Springer-Verlag
Publisher Date	2006-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Polymers and organic compounds Conductivity phenomena in semiconductors and insulators Magnetic phase boundaries Saturation moments and magnetic susceptibilities Characterization and Evaluation of Materials Condensed Matter Magnetism, Magnetic Materials
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Condensed Matter Physics Materials Science

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