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  1. Journal of Inorganic and Organometallic Polymers and Materials
  2. Journal of Inorganic and Organometallic Polymers and Materials : Volume 25
  3. Journal of Inorganic and Organometallic Polymers and Materials : Volume 25, Issue 6, November 2015
  4. Synthesis of Soluble Ferrocene-Based Polythiophenes and Their Properties
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Journal of Inorganic and Organometallic Polymers and Materials : Volume 27
Journal of Inorganic and Organometallic Polymers and Materials : Volume 26
Journal of Inorganic and Organometallic Polymers and Materials : Volume 25
Journal of Inorganic and Organometallic Polymers and Materials : Volume 25, Issue 6, November 2015
Physically Blended and Chemically Modified Polyurethane Hybrid Nanocoatings Using Polyhedral Oligomeric Silsesquioxane Nano Building Blocks: Surface Studies and Biocompatibility Evaluations
Albumin Conjugating Amino Acid Schiff-Base Metal Complexes for Scavenging Superoxide Anion Radical
Fast and Reversible Detection of Nitrobenzene Vapour by a Fluorescent Metal–Organic Framework Templated by Ionic Liquid
Preparation and Properties of Pinacolborane Modified Polycarbosilane as SiC Fiber Precursor
A Green Biosensing Matrix Based on Chitosan and Graphene nanohybrid for the Immobilization of Glucose Oxidase: Synthesis and Property evaluation
Preparation, Characterization and Application of Hybrid Materials Having Multifunctional Properties
One-Pot Synthesis of Oligo-Ladder Phenylsilsesquioxanes via Pyridine–Silicon Adduct Formation at Aqueous–Organic Liquid Boundary
Investigation of Cation Distribution and Microstructure of Nano Ferrites Prepared by Different Wet Methods
Polynuclear Loop-Modified Molybdenum Arsenate: Synthesis, Structure and Property
Mono-nuclear and Hexa-nuclear Iron(III) Compounds Based on Phenol-Pyrazole Ligand: Synthesis, Crystal Structure and Magnetic Properties
A Cationic Two-Dimensional Zn(II) Coordination Polymer, Crystal Structure and Fluorescence Emission
Structure and Spectral Characterization of Coordination Polymers Constructed by CuCN and Aliphatic Diamines
Chemical Mechanical Polishing for SiO$_{2}$ Film Using Polystyrene@ceria (PS@CeO$_{2}$) Core–Shell Nanocomposites
Synthesis of Organotin Polyamine Ethers Containing Thiamine (Vitamin B$_{1}$) and Preliminary Ability to Inhibit Select Cancer Cell Lines
Organic Carboxylate Ligands Tuned Structural Variations of Three New Cd(II) Coordination Polymers with Guanazole as Co-ligand
3D Hierarchical Flower-Like Bi$_{2}$WO$_{6}$ Microparticles Doped with Uranyl Group: Characterization and Higher Photocatalytic Activity
Synthesis, Crystal Structure, Physical Properties and Theoretical Calculations of a New One-Dimensional Ni(II) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative Ligand and Sulfate
Characterization of Gamma Irradiated Low and High Density Polyethylene Using the FTIR and DSC Technique
Synthesis and Thermal Behaviour of Novel Aliphatic/Aromatic Hepta-Cyclopentyl Bridged Polyhedral Oligomeric Silsesquioxanes (POSSs)/Polystyrene (PS) Nanocomposites
Preparation of EuBO$_{3}$ Microspindles from Europium Coordination Polymer
Morphological and Field Emission Properties of ZnO Deposited MWCNT by RF Sputtering and PECVD
3D-Interpenetrating Frameworks of $^{3}$∞[Cu$_{2}$(CN)$_{4}$(Me$_{3}$Pb)$_{2}$(bpy)] Containing the Rhombic [Cu$_{2}$(µ$_{3}$-CN)$_{2}$] Motifs
Magnetron Sputtered AZO Thin Film Preparation for the Solar Cells Applications
Synthesis, Crystal Structures, Photocatalysis for Rhodamine B Degradation of a Organobismuth (V) Dithiocarbamate Polymer [PhBiS$_{2}$CN(C$_{2}$H$_{5}$)$_{2}$Cl]$_{n}$
The Research of the Synthesis Mechanism and Synthesis Process of High Crystallinity Globular h-BN
The Effect of Doping and Confinement on the Adsorption of Pt on CNTs upon Be, B, N and O Doping: A Theoretical Study
Synthesis of Soluble Ferrocene-Based Polythiophenes and Their Properties
Influence of Ce Doping Concentration on the Structural and Optical Properties of Sol–Gel Derived ZnO:Ce Nanostructures
H$_{2}$S Adsorption Characteristics on Cu$_{2}$O Nanostructures: A First-Principles Study
Carbonization, Impregnation and Activation Synthesis for Sulfur Dioxide Adsorbent Capacity of Carbon
Influence of Kaolin on the Sintering of Glass Powder to Glass–Ceramics
Catalytic Reduction of 2-Nitroaniline in Aqueous Medium Using Silver Nanoparticles Functionalized Polymer Microgels
Detonation Synthesis and Friction-Wear Test of Carbon-Encapsulated Copper Nanoparticles
Electrocatalytic Properties of Vanadyl Complex in Graphite Nanocomposite and its Enhanced Electrochemical Catalysis Properties for Levodopa Oxidation
Methyl orange removal from wastewater using [Zn$_{2}$(oba)$_{2}$(4-bpdh)]·3DMF metal–organic frameworks nanostructures
Journal of Inorganic and Organometallic Polymers and Materials : Volume 25, Issue 5, September 2015
Journal of Inorganic and Organometallic Polymers and Materials : Volume 25, Issue 4, July 2015
Journal of Inorganic and Organometallic Polymers and Materials : Volume 25, Issue 3, May 2015
Journal of Inorganic and Organometallic Polymers and Materials : Volume 25, Issue 2, March 2015
Journal of Inorganic and Organometallic Polymers and Materials : Volume 25, Issue 1, January 2015
Journal of Inorganic and Organometallic Polymers and Materials : Volume 24
Journal of Inorganic and Organometallic Polymers and Materials : Volume 23
Journal of Inorganic and Organometallic Polymers and Materials : Volume 22
Journal of Inorganic and Organometallic Polymers and Materials : Volume 21
Journal of Inorganic and Organometallic Polymers and Materials : Volume 20
Journal of Inorganic and Organometallic Polymers and Materials : Volume 19
Journal of Inorganic and Organometallic Polymers and Materials : Volume 18
Journal of Inorganic and Organometallic Polymers and Materials : Volume 17
Journal of Inorganic and Organometallic Polymers and Materials : Volume 16
Journal of Inorganic and Organometallic Polymers and Materials : Volume 15
Journal of Inorganic and Organometallic Polymers and Materials : Volume 14
Journal of Inorganic and Organometallic Polymers and Materials : Volume 13
Journal of Inorganic and Organometallic Polymers and Materials : Volume 12
Journal of Inorganic and Organometallic Polymers and Materials : Volume 11
Journal of Inorganic and Organometallic Polymers and Materials : Volume 10
Journal of Inorganic and Organometallic Polymers and Materials : Volume 9
Journal of Inorganic and Organometallic Polymers and Materials : Volume 8
Journal of Inorganic and Organometallic Polymers and Materials : Volume 7

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Synthesis of Soluble Ferrocene-Based Polythiophenes and Their Properties

Content Provider Springer Nature Link
Author Khalid, Hamad Wang, Li Yu, Haojie Akram, Muhammad Abbasi, Nasir M. Sun, Ruoli Saleem, Muhammad Chen, Yongsheng
Copyright Year 2015
Abstract Ferrocene-based polythiophenes are the promising class of the functional materials, but mostly the polythiophenes are insoluble in common solvents except some derivatives of polythiophenes like poly(3-hexylthiophene) (P3HT). Herein, two new ferrocene-based thiophene monomers, 2-(thiophen-3-yl) ethyl ferrocenoate and 2-(thiophen-3-yl) methyl ferrocenoate were synthesized and copolymerized with 3-hexylthiophene (3HT) respectively. The resulting polymers were soluble (in common organic solvents) and processable. The synthesis and the molecular weights were confirmed by the $^{1}$H-NMR and GPC studies respectively. Poly (TEF-co-3HT) was subjected to study the electrochemical properties in comparison of respective monomers and ferrocene. It was found that the resulting copolymer had the combined redox properties of its monomers. Also, very interestingly, the copolymer showed improved reversible redox properties which were not only better than its parent monomers but even better than the pure ferrocene. Photoemission spectra of P3HT and Poly (TEF-co-3HT) were also rerecorded and compared with each other.
Starting Page 1511
Ending Page 1520
Page Count 10
File Format PDF
ISSN 15741443
Journal Journal of Inorganic and Organometallic Polymers and Materials
Volume Number 25
Issue Number 6
e-ISSN 15741451
Language English
Publisher Springer US
Publisher Date 2015-08-28
Publisher Place New York
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword Ferrocene Thiophene Soluble Redox Photoemission Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type Text
Resource Type Article
Subject Materials Chemistry Polymers and Plastics
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