NDLI: Characterization of Diatomite Platelets and Its Application for In Situ Atom Transfer Radical Random Copolymerization of Styrene and Butyl Acrylate: Normal Approach

Content Provider	Springer Nature Link
Author	Khezri, Khezrollah Fazli, Yousef
Copyright Year	2016
Abstract	Pristine mesoporous diatomite platelets were employed to prepare poly(styrene-co-butyl acrylate)/diatomite composites. Diatomite platelets were used for in situ copolymerization of styrene and butyl acrylate by ATRP to synthesize tailor-made poly(styrene-co-butyl acrylate) nanocomposites. XRF analysis, FTIR spectroscopy, TGA, nitrogen adsorption/desorption isotherm, SEM, and TEM were employed for evaluating inherent properties of pristine diatomite nanoplatelets. Conversion and molecular weight determinations were performed using GC and SEC respectively. Addition of 3 wt% pristine mesoporous diatomite platelets leads to increase of conversion from 65 to 78%. Molecular weight of copolymer chains increases from 15,500 to 19,000 by addition of 3 wt% pristine mesoporous diatomite; however, dispersity increases from 1.1 to 1.4. Copolymers composition was evaluated using $^{1}$H NMR spectroscopy. Increasing thermal stability of the nanocomposites is demonstrated by TGA. DSC shows an increase in glass transition temperature from 34.6 to 38.8 °C by adding 3 wt% of mesoporous diatomite platelets.
Starting Page	266
Ending Page	274
Page Count	9
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	27
Issue Number	1
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2016-11-22
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Mesoporous diatomite platelets Nanocomposite Poly(styrene-co-butyl acrylate) In situ ATRP Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

SR&NI Atom Transfer Radical Random Copolymerization of Styrene and Methyl Methacrylate: Incorporation of Diatomite Platelets

Synthesis and Characterization of Silica Aerogel-Dispersed Random Poly(styrene-co-butyl acrylate) Nanocomposites by Atom Transfer Radical Copolymerization: A Reverse Approach

Effect of Mesoporous Diatomite Particles on the Kinetics of SR&NI ATRP of Styrene and Butyl Acrylate

Use of clay-anchored reactive modifier for the synthesis of poly (styrene-co-butyl acrylate)/clay nanocomposite via in situ AGET ATRP

SR&NI atom transfer radical random copolymerization of styrene and butyl acrylate in the presence of MPS-functionalized silica aerogel nanoparticles : Investigating thermal properties

Control of monodisperse particle size of styrenic-acrylate copolymers in dispersion copolymerization

Preparation of block copolymers of polystyrene and poly (t-butyl acrylate) of various molecular weights and architectures by atom transfer radical polymerization

Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization

Characterization of poly(butyl acrylate) diols prepared via atom transfer radical polymerization and subsequent modification

Characterization of Diatomite Platelets and Its Application for In Situ Atom Transfer Radical Random Copolymerization of Styrene and Butyl Acrylate: Normal Approach

Similar Documents

SR&NI Atom Transfer Radical Random Copolymerization of Styrene and Methyl Methacrylate: Incorporation of Diatomite Platelets

Synthesis and Characterization of Silica Aerogel-Dispersed Random Poly(styrene-co-butyl acrylate) Nanocomposites by Atom Transfer Radical Copolymerization: A Reverse Approach

Effect of Mesoporous Diatomite Particles on the Kinetics of SR&NI ATRP of Styrene and Butyl Acrylate

Use of clay-anchored reactive modifier for the synthesis of poly (styrene-co-butyl acrylate)/clay nanocomposite via in situ AGET ATRP

SR&NI atom transfer radical random copolymerization of styrene and butyl acrylate in the presence of MPS-functionalized silica aerogel nanoparticles : Investigating thermal properties

Control of monodisperse particle size of styrenic-acrylate copolymers in dispersion copolymerization

Preparation of block copolymers of polystyrene and poly (t-butyl acrylate) of various molecular weights and architectures by atom transfer radical polymerization

Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization

Characterization of poly(butyl acrylate) diols prepared via atom transfer radical polymerization and subsequent modification

Characterization of Diatomite Platelets and Its Application for In Situ Atom Transfer Radical Random Copolymerization of Styrene and Butyl Acrylate: Normal Approach