NDLI: Preparation, Infra-red, MAS-NMR and Structural Characterization of a New Copper Based Inorganic–Organic Hybrid Compound: [C$_{5}$H$_{6}$N$_{2}$Cl]$_{2}$CuCl$

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Preparation, Infra-red, MAS-NMR and Structural Characterization of a New Copper Based Inorganic–Organic Hybrid Compound: [C$_{5}$H$_{6}$N$_{2}$Cl]$_{2}$CuCl$_{4}$

Content Provider	Springer Nature Link
Author	Karaa, Najla Hamdi, Besma Oueslati, Abderrazek Ben Salah, Abdelhamid Zouari, Ridha
Copyright Year	2010
Abstract	The ionic salt [2(C$_{5}$H$_{6}$N$_{2}$Cl)$^{+}$], [CuCl$_{4}$]$^{2−}$ complex of copper(II) has been synthesized and characterized. The X-ray diffraction analysis with a single crystal of this compound showed that the title compound (4-amino-2-chloropyridinium)$_{2}$CuCl$_{4}$ [(CAP)$_{2}$CuCl$_{4}$], crystallized at room temperature in the monoclinic system, space group C$_{2/c}$ (N°.15) and the following : a = 16.0064 (2) Å; b = 7.7964 (10) Å; c = 14.7240 (2) Å; β = 102.497 (10)°; V = 1793.91 (4) Å$^{3}$ and Z = 4. The structure was solved by using 1,589 independent reflections down to R value of 0.021. The unit cell is made up of tetrachlorocuprate(II) anions and 4-amino-2-chloropyridinium cations linked together by an extensive hydrogen bond network of types N–H···Cl (N: pyridinium) and N–H···Cl (N: amine), and cation-lone pair of nitrogen element interactions. Solid state NMR spectra showed one and five isotropic resonances, $^{63}$Cu and $^{13}$C, respectively, confirming the solid state structure determined by X-ray diffraction. Impedance spectroscopy study, reported for single crystal, revealed that the conduction in the material was due to a hopping process. This work aims to reveal the thermal properties of a new copper(II) based organic–inorganic hybrid and the conductivity properties that these compounds exhibit.
Starting Page	746
Ending Page	754
Page Count	9
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	20
Issue Number	4
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2010-09-21
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Bis(4-amino-2-chloropyridinium) tetrachlorocuprate(II) Organic–inorganic hybrid X-ray diffraction Infrared spectroscopy Nuclear magnetic resonance Thermal analysis Impedance spectroscopy Conductivity Dielectric Polymer Sciences Organic Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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