NDLI: Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal

Content Provider	Springer Nature Link
Author	Chai, Wen Xiang Song, Li Lin, Jian Shu, Kang Ying Qin, Lai shun Shi, Hong sheng Guo, Jia Yu
Copyright Year	2012
Abstract	A flexible polycarboxyl ligand of tetrahydrofuran-2,3,4,5-tetracarboxylic acid (H$_{4}$THFTCA) and a common rigid aromatic ligand of 1,10-phenanthroline (phen) have been successfully co-assembled with Cu(NO$_{3}$)$_{2}$·3H$_{2}$O to give out a novel 3D supramolecular metal–organic framework (MOF) compound, [Cu$_{2}$(THFTCA)(phen)(H$_{2}$O)$_{2}$·CH$_{3}$CH$_{2}$OH·3H$_{2}$O]$_{ n }$ (1), by a solution self-assembly process. Compound 1 has been characterized as a 2D layered coordination polymer constructed by THFTCA$^{4−}$ and Cu$^{2+}$ ions, and the layer present a novel (3.5$^{2}$)(3$^{2}$.5$^{3}$.6$^{4}$.7) topological network. Interestingly, the layers are fused each other via strong π–π stacking interactions among adjacent ligands of the terminal phen, so that a 3D supramolecular MOF with 1D rhomboidal tunnels array is formed. The thermogravimetric analysis and corresponding powder X-ray diffraction analysis have revealed that the tunnels structure of 1 could be retained after all guest molecules are removed, and the framework could resist the collapse even heating up to 210 °C. An opinion has also been proposed that the larger accessible volume of the guests means the larger stress on the backbone of the MOF after the guests are removed, and the stress is harmful to the stability of the supramolecular porous structure. Finally, the application properties based on the porous structure have also been primarily evaluated.
Starting Page	1263
Ending Page	1270
Page Count	8
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	22
Issue Number	6
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2012-08-14
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Crystal structure Topological network π–π stacking Supramolecular MOF Thermal stability of tunnels Gas adsorption Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels

A PtS-like 3D Framework Constructed from 1,4-Phenylenediacetic Acid: Synthesis, Structure and Physical Properties

Solvothermal Synthesis, Crystal Structure and DNA Binding Studies of a 3D Supramolecular Complex {[Cu(phen)CN][Cu(phen)][Cu(CN)$_{2}$]}$_{ n }$ Assembled by Double Curvy Chains

A New Nitrosyl-bridged Bimetallic Nitroprusside Complex: Synthesis, Crystal Structure, Supramolecular Self-assembly and Spectral Behavior of Interactions with DNA

Synthesis, Crystal Structures and Thermal Stabilities of Lanthanide Coordination Polymers with 5-Nitroisophthalate

Synthesis of a New Interpenetrated Mixed Ligand Ni(II) Metal–Organic Framework: Structural, Thermal and Fluorescence Studies and its Thermal Decomposition to NiO Nanoparticles

A Novel Binodal (4,9)-Connected 3D Calcium Coordination Polymer: Synthesis, Characterization, Thermal Stability and Luminescent Properties

Four New Ag(I) Coordination Polymers: Synthesis, Crystal Structures and Thermal Stability

Zinc(II) Metal–Organic Framework with Nano-Sized Channels Based on Paddle-Wheel Units

Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels

Similar Documents

Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels

A PtS-like 3D Framework Constructed from 1,4-Phenylenediacetic Acid: Synthesis, Structure and Physical Properties

Solvothermal Synthesis, Crystal Structure and DNA Binding Studies of a 3D Supramolecular Complex {[Cu(phen)CN][Cu(phen)][Cu(CN)$_{2}$]}$_{ n }$ Assembled by Double Curvy Chains

A New Nitrosyl-bridged Bimetallic Nitroprusside Complex: Synthesis, Crystal Structure, Supramolecular Self-assembly and Spectral Behavior of Interactions with DNA

Synthesis, Crystal Structures and Thermal Stabilities of Lanthanide Coordination Polymers with 5-Nitroisophthalate

Synthesis of a New Interpenetrated Mixed Ligand Ni(II) Metal–Organic Framework: Structural, Thermal and Fluorescence Studies and its Thermal Decomposition to NiO Nanoparticles

A Novel Binodal (4,9)-Connected 3D Calcium Coordination Polymer: Synthesis, Characterization, Thermal Stability and Luminescent Properties

Four New Ag(I) Coordination Polymers: Synthesis, Crystal Structures and Thermal Stability

Zinc(II) Metal–Organic Framework with Nano-Sized Channels Based on Paddle-Wheel Units

Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels