NDLI: Synthesis of Metal-containing Polymers via Ring Opening Metathesis Polymerization (ROMP). Part II: Polymers Containing Transition Metals

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Synthesis of Metal-containing Polymers via Ring Opening Metathesis Polymerization (ROMP). Part II: Polymers Containing Transition Metals

Content Provider	Springer Nature Link
Author	Dragutan, Ileana Dragutan, Valerian Fischer, Helmut
Copyright Year	2008
Abstract	Following from Part I (this journal, 18(1), 2008), dedicated to main group metal containing polymers obtained by ROMP, the application of the same progressive concept to prepare polymers having this time transition metals in the side- or main-chain is here critically overviewed. These TMC polymers were produced through ROMP reactions promoted by Schrock’s Mo-carbene or the Grubbs’ Ru-carbene catalysts, the most recent and unique methodology for obtaining wished for structures. While discussing main aspects of these target-driven syntheses, as well as properties and applications of the neutral and cationic transition metal containing polymers, emphasis is laid upon organoiron macromolecules based on ferrocene scaffolds. Special attention is given to electrochemical behavior and thermal characteristics. Topics also cover polymers with other transition metals such as Co, Ni, Ru, Pd and Pt, which are important for generating zero valent metal nanoclusters in polymer films. Finally highlighted are some illustrative examples of metal-linked, metallodendrimers and hyperbranched, dendritic and star polymers.
Starting Page	311
Ending Page	324
Page Count	14
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	18
Issue Number	3
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2008-06-20
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Organometallic polymers ROMP Ferrocene Transition metals Hybrid materials Hyperbranched and dendritic architectures Star polymers Polymer Sciences Organic Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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