NDLI: 3D Coordination Network of Ag(I) Ions with μ $

Content Provider	Springer Nature Link
Author	Rana, Abhinandan Bera, Madhusudan Chowdhuri, Durga Sankar Hazari, Debdoot Jana, Swapan Kumar Zangrando, Ennio Dalai, Sudipta
Copyright Year	2011
Abstract	A new 3D silver complex [Ag(mela)(H$_{2}$O)(NO$_{3}$)]$_{n}$ (1) (mela = melamine or 2,4,6-triaminotriazine) is synthesized and characterized by single crystal X-ray diffraction, IR, and elemental analysis. The structural characterization shows that the compound crystallizes in space group C c, a = 8.181(2), b = 10.269(3) c = 11.347(3) Å, β = 105.88(2)°, Z = 4. Out of several structurally characterized transition metal compounds comprising melamine, the titled complex represents a rare example of μ $_{ 3 }$-melamine coordination mode realized through the heterocycle nitrogen donors. The fluorescent property of complex 1 was investigated and the mechanism was validated by means of a density functional theory (DFT) calculation.A new 3D silver complex was synthesized using the 2,4,6-triaminotriazine ligand. The X-ray structural analysis shows a highly distorted trigonal bipyramidal geometry of Ag(I) ion with a rare μ$_{3}$-coordination mode of the ligand achieved through the heterocyclic nitrogen donors. Emission study reveals intraligand and ligand-to-metal charge transfer in the complex.
Starting Page	360
Ending Page	368
Page Count	9
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	22
Issue Number	2
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2011-11-11
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Coordination polymer Silver(I) Melamine Hydrogen bond Photoluminescence Organic Chemistry Inorganic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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