NDLI: Two Energetic Cobalt(II) Coordination Polymers Derived from Isomeric Ligands

Content Provider	Springer Nature Link
Author	Zhu, Da Liang Yue, Qiu Yan Wang, Jue Guo, Meng Yue Miao, Li Li Qiu, Li Jun Li, Qiao Yun Yang, Gao Wen
Copyright Year	2016
Abstract	Isomer is sometimes fundamental to the formation of the resulting compounds. The design and preparation of coordination compounds based on isomers is of tremendous paramount since they have a lot in common but simultaneously some difference, which can lead to variation of both the topologies and properties. Solvothermal reactions of Hn-pytza (n = 3, 4) with Co(ClO$_{4}$)$_{2}$·6H$_{2}$O, afforded two interesting coordination polymers, one dimensional [Co(3-pytza)$_{2}$(H$_{2}$O)$_{2}$]$_{n}$·2nH$_{2}$O (1) and three dimensional [Co(4-pytza)$_{2}$]$_{n}$ (2), where Hn-pytza = 5-(n-pyridyl)tetrazole-2-acetic acid (n = 3, 4). The thermal decomposition behavior of the two compounds were characterized by the differential scanning calorimetry (DSC) and thermogravimetric-differential thermogravimetric (TG-DTG), showing [Co(4-pytza)$_{2}$]$_{n}$ is superior to [Co(3-pytza)$_{2}$(H$_{2}$O)$_{2}$]$_{n}$·2nH$_{2}$O in terms of energetic performance. Furthermore, the entropy of activation (∆S), enthalpy of activation (∆H), and free energy of activation (∆G) were calculated, as well.
Starting Page	616
Ending Page	622
Page Count	7
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	26
Issue Number	3
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2016-02-15
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Co(II) Isomer Crystal structure Energetic material Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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