NDLI: Polymerization of Methacrylates Containing Cationic Cyclopentadienyliron Moieties

Content Provider	Springer Nature Link
Author	Abd El Aziz, Alaa S. Todd, Erin K. Ma, Guozhang DiMarti, Joseph
Copyright Year	2000
Abstract	A novel approach to the synthesis of polymethacrylates containing cationic cyclopentadienyliron moieties pendent to their side chains was accomplished via the use of π-coordinated organoiron complexes. The complexed methacrylates were polymerized in the presence of AIBN to give soluble organoiron polymethacrylates (6a and 6b, 10, 14a and 14b) in 80–90% yields. Photolytic demetallation of the organoiron polymers allowed for the isolation of their organic analogues (7a and 7b, 11, 15a and 15b) whose weight average molecular weights ranged from 48,500 to 68,300.
Starting Page	265
Ending Page	272
Page Count	8
File Format	PDF
ISSN	10530495
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	10
Issue Number	4
e-ISSN	15728870
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2000-01-01
Publisher Place	New York
Access Restriction	Subscribed
Subject Keyword	Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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Polymerization of Methacrylates Containing Cationic Cyclopentadienyliron Moieties