NDLI: Synthesis, Structure and Fluorescence Spectra Study of a Supramolecular Zinc(II) Complex

Content Provider	Springer Nature Link
Author	Xu, Xue Ting Bai, Feng Ying Zou, Wei Xing, Yong Heng
Copyright Year	2013
Abstract	A new structural supramolecular zinc(II) complex (1), [Zn(H$_{2}$O)$_{6}$]$^{2+}$[Zn(4,4′-bipy)(SO$_{4}$)$_{2}$(H$_{2}$O)$_{2}$]$^{2−}$[Zn(4,4′-bipy)(SO$_{4}$)(H$_{2}$O)$_{3}$] is synthesized in mixed solvent system at room temperature. The complex was characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. Structural analyses reveal that the complex is crystallized in the triclinic system with P1 space group. Cell parameters: a = 7.3145 (15) Å, b = 11.194 (2) Å, c = 11.442 (2) Å, α = 72.48 (3)°, β = 73.78 (3)°, γ = 83.39 (3)°, V = 857.3 (3) Å$^{3}$. Zn atoms (Zn1, Zn2 and Zn3) are all six-coordinated, however, the coordination environments of them are different. Owning to the abundant intro- and inter- hydrogen bonding interactions, the adjacent molecular units were connected to form a 2D supramolecular chain, and the two adjacent chains were furthermore linked to form a 3D supermolecular network structure via the hydrogen bonds. In addition, it is found that the complex has potential applications as fluorescent-emitting materials due to the strong fluorescence.
Starting Page	450
Ending Page	456
Page Count	7
File Format	PDF
ISSN	15741443
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume Number	24
Issue Number	2
e-ISSN	15741451
Language	English
Publisher	Springer US
Publisher Date	2013-11-21
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Zinc complex Synthesis Structure Fluorescence spectrum Inorganic Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Polymers and Plastics

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