NDLI: Fluorescence Properties and Dipole Moments of Novel Fused Thienobenzofurans. Solvent and Structural Effects

Content Provider	Springer Nature Link
Author	Aaron, Jean Jacques Párkányi, Cyril Adenier, Alain Potin, Caroline Zajíčková, Zuzana Martínez, Omar R. Svoboda, Jiří Pihera, Pavel Váchal, Petr
Copyright Year	2011
Abstract	The electronic absorption, fluorescence excitation and emission spectra, and fluorescence quantum yields of novel fused thienobenzofurans, including thieno[3,2-b][1]benzofuran (1), [1]benzothieno[3,2-b]furan (2), and [1]benzothieno[3,2-b][1]benzofuran (3), were recorded in fourteen solvents of different polarities at room temperature. Compound 2 was not fluorescent. Experimental ground-state dipole moments of compounds 1–3 were measured in benzene at 298 K and compared with the corresponding theoretical dipole moment values. The solvent effects on the electronic absorption and fluorescence spectra of these thienobenzofurans were quantitatively investigated by means of solvatochromic correlations based on the Kawski-Chamma-Viallet and McRae equations. A weak negative solvatochromic behavior was found for these compounds, showing that their dipole moments are slightly lower in the excited singlet-state than in the ground-state. Kamlet-Abboud-Taft multiparameter relationships were also established for electronic absorption and fluorescence wavenumbers, and fluorescence quantum yields in most solvents, demonstrating the occurrence of specific solute-solvent interactions.
Starting Page	2133
Ending Page	2141
Page Count	9
File Format	PDF
ISSN	10530509
Journal	Journal of Fluorescence
Volume Number	21
Issue Number	6
e-ISSN	15734994
Language	English
Publisher	Springer US
Publisher Date	2011-07-13
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Fused thienobenzofurans Electronic absorption spectra Fluorescence Dipole moments Solvatochromic correlations Kamlet-Abboud-Taft relationships Quantum-chemical calculations Biomedicine general Biochemistry Biophysics and Biological Physics Analytical Chemistry Biotechnology
Content Type	Text
Resource Type	Article
Subject	Sociology and Political Science Spectroscopy Law Biochemistry Clinical Biochemistry Clinical Psychology

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

“Estimation of Ground and Excited State Dipole Moments of aryl Boronic acid Derivative by Solvatochromic Shift Method”

Solvent Effect on Absorption and Fluorescence Spectra of Three Biologically Active Carboxamides (C$_{1}$, C$_{2}$ and C$_{3}$). Estimation of Ground and Excited State Dipole Moment from Solvatochromic Method Using Solvent Polarity Parameters

Solvatochromic Studies of Fluorescent Azo Dyes: Kamlet-Taft (π*, α and β) and Catalan (S$_{pp}$, S$_{A}$ and S$_{B}$) Solvent Scales Approach

Solvent Effects on the Spectroscopic Properties of Styrylquinolinium Dyes Series

Optimization in Solvent Selection for Chlorin e6 in Photodynamic Therapy

Solvent Effects on the Electronic Absorption and Fluorescence Spectra of HNP: Estimation of Ground and Excited State Dipole Moments

On the Photophysicochemical Properties of Selected Fluoroquinolones: Solvatochromic and Fluorescence Spectroscopy Study

Kamlet-Taft and Catalan Studies of Some Novel Y-Shaped Imidazole Derivatives

Estimation of Ground-State and Singlet Excited-State Dipole Moments of Substituted Schiff Bases Containing Oxazolidin-2-one Moiety through Solvatochromic Methods

Fluorescence Properties and Dipole Moments of Novel Fused Thienobenzofurans. Solvent and Structural Effects

Similar Documents

“Estimation of Ground and Excited State Dipole Moments of aryl Boronic acid Derivative by Solvatochromic Shift Method”

Solvent Effect on Absorption and Fluorescence Spectra of Three Biologically Active Carboxamides (C$_{1}$, C$_{2}$ and C$_{3}$). Estimation of Ground and Excited State Dipole Moment from Solvatochromic Method Using Solvent Polarity Parameters

Solvatochromic Studies of Fluorescent Azo Dyes: Kamlet-Taft (π*, α and β) and Catalan (S$_{pp}$, S$_{A}$ and S$_{B}$) Solvent Scales Approach

Solvent Effects on the Spectroscopic Properties of Styrylquinolinium Dyes Series

Optimization in Solvent Selection for Chlorin e6 in Photodynamic Therapy

Solvent Effects on the Electronic Absorption and Fluorescence Spectra of HNP: Estimation of Ground and Excited State Dipole Moments

On the Photophysicochemical Properties of Selected Fluoroquinolones: Solvatochromic and Fluorescence Spectroscopy Study

Kamlet-Taft and Catalan Studies of Some Novel Y-Shaped Imidazole Derivatives

Estimation of Ground-State and Singlet Excited-State Dipole Moments of Substituted Schiff Bases Containing Oxazolidin-2-one Moiety through Solvatochromic Methods

Fluorescence Properties and Dipole Moments of Novel Fused Thienobenzofurans. Solvent and Structural Effects