NDLI: Reactions of ReH3(CO)(PMe2Ph)3 with Metallic Lewis Acids. Synthesis and Structural Characterization of Hydrido-Bridged Heterometallic Rhenium-Gold, Rhenium-Silver, and Rhenium-Copper Complexes

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Reactions of ReH3(CO)(PMe2Ph)3 with Metallic Lewis Acids. Synthesis and Structural Characterization of Hydrido-Bridged Heterometallic Rhenium-Gold, Rhenium-Silver, and Rhenium-Copper Complexes

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Journal of Cluster Science : Volume 10

Journal of Cluster Science : Volume 9

Journal of Cluster Science : Volume 8

Reactions of ReH3(CO)(PMe2Ph)3 with Metallic Lewis Acids. Synthesis and Structural Characterization of Hydrido-Bridged Heterometallic Rhenium-Gold, Rhenium-Silver, and Rhenium-Copper Complexes

Content Provider	Springer Nature Link
Author	Luo, Steven Burns, Carol J. Kubas, Gregory J. Bryan, Jeffrey C. Crabtree, Robert H.
Copyright Year	2000
Abstract	This contribution presents a study of the reactions of ReH$_{3}$(CO)(PMe$_{2}$Ph)$_{3}$ (1) with a variety of metallic Lewis acids of the coinage metals to form hydrido-bridged heterometallic rhenium-gold, rhenium-silver, and rhenium-copper complexes. The reaction of 1 with AuCl(PPh$_{3}$) proceeds with elimination of hydrogen to give the hydrido-bridged heterobinuclear rhenium-gold complex (PMe$_{2}$Ph)$_{3}$(CO)ClRe(μ-H)Au(PPh$_{3}$) (2). In contrast, the reactions of 1 with AgPF$_{6}$, [Cu(CH$_{3}$CN)$_{4}$]PF$_{6}$ or CuCl proceed without elimination of hydrogen to give the hydrido-bridged heterotrinuclear rhenium-silver and rhenium-copper complexes [(PMe$_{2}$Ph)$_{3}$(CO)HRe(μ-H)$_{2}$M(μ-H)$_{2}$ReH(CO)(PMe$_{2}$Ph)$_{3}$]PF$_{6}$ (M=Ag (3), Cu (4)) and the hydrido-bridged heterotetranuclear rhenium-copper complex (PMe$_{2}$Ph)$_{3}$(CO)HRe(μ-H)$_{2}$Cu(μ-Cl)$_{2}$Cu(μ-H)$_{2}$ReH(CO)(PMe$_{2}$Ph)$_{3}$ (5), respectively. The molecular structures of compounds 2 and 3 have been determined by single-crystal X-ray diffraction studies. Crystallographic data for 2: monoclinic, space group P2$_{1}$2$_{1}$2$_{1}$, a=12.804(2) Å, b=13.512(2) Å, c=24.312(3) Å, V=4206(1) Å$^{3}$, Z=4, and R=0.042. Crystallographic data for 3: monoclinic, space group C2/c, a=24.212(6) Å, b=13.098(3) Å, c=20.177(5) Å, b=116.40(2)°, V=5732(2) Å$^{3}$, Z=4, and R=0.044. The X-ray crystal structure of 2 exhibits a short contact (2.798(12) Å) between the gold atom and the CO ligand that is primarily bound to the adjacent rhenium atom, suggesting an incipient semibridging relationship.
Starting Page	189
Ending Page	216
Page Count	28
File Format	PDF
ISSN	10407278
Journal	Journal of Cluster Science
Volume Number	11
Issue Number	1
e-ISSN	15728862
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2000-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Biochemistry Condensed Matter Physics Materials Science

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Reactions of ReH3(CO)(PMe2Ph)3 with Metallic Lewis Acids. Synthesis and Structural Characterization of Hydrido-Bridged Heterometallic Rhenium-Gold, Rhenium-Silver, and Rhenium-Copper Complexes

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