NDLI: Reactions of K$_{2}$[Fe$_{3}$Q(CO)$_{9}$] (Q = Se, Te) with AsI$_{3}$: Synthesis and Structures of the First {Fe$_{3}$TeAs} Clusters with Capping µ$_{3}$-AsI and Bridging µ$_{6}$,κ$^{3}$:κ$^{3}$-As$

Please wait, while we are loading the content...

Synthesis of Im$_{3}$[Mo$_{3}$(μ$_{3}$-S)(μ-S$_{2}$)$_{3}$Br$_{6}$]Br (Im = 1-ethyl-3-methylimidazolium) in Ionic Liquid: A New Way of Breaking Up Chalcogenide Cluster Coordination Polymers

On the Electronic Structure of Organometallic Palladium Clusters of Medium and Large Size: A Theoretical Study

Advances in the Engineering of Near Infrared Emitting Liquid Crystals and Copolymers, Extended Porous Frameworks, Theranostic Tools and Molecular Junctions Using Tailored Re$_{6}$ Cluster Building Blocks

Linkage Isomerism in [Mo$_{3}$(μ$_{3}$-S)(μ$_{2}$-SSe)$_{3}$(dtp)$_{3}$]Cl: Preparation and Characterization of Two Isomers with Different Coordination Mode of the μ$_{2}$-SSe Ligand

Synthesis of the Stereoisomeric Clusters 1,2-Os$_{3}$(CO)$_{10}$(trans-dpmn) and 1,2-Os$_{3}$(CO)$_{10}$(cis-dpmn) [where dpmn = 2,3-bis(diphenylphosphinomethyl)-5-norbornene]: DFT Evaluation of the Isomeric Clusters 1,2-Os$_{3}$(CO)$_{10}$(dpmn) and Isomer-Dependent Diphosphine Ligand Activation

New Tungsten Cluster Based Contrast Agents for X-ray Computed Tomography

Synthesis and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Clusters, [Mo$_{3}$O$_{ n }$S$_{4−n }$ (Tm)$_{3}$]$^{+}$ (n = 0–3)

1,1-Cyclohexanediacetate as New Bridging Ligand for Assembling of Homo- and Heterometallic Molecular Complexes with Cu 3 II , Cu 2 II Ln 2 III (Ln = Sm or Gd) and Ni 2 II Gd 2 III Cores: Synthesis, Structure and Magnetic Properties

Formation of 3,5-Dithio-cyclopentenyl Ligand on Fe$_{2}$(CO)$_{6}$ Support from Photochemical Reaction of Internal Acetylenes with [Fe(CO)$_{5}$] in Presence of CS$_{2}$

Backbone Modified Small Bite-Angle Diphosphines: Synthesis, Structure, Fluxionality and Regioselective Thermally-Induced Transformations of Ru$_{3}$(CO)$_{10}${µ-Ph$_{2}$PCH(Me)PPh$_{2}$}

Thermal Detection, Synthesis, and Structural Characterization of Compounds in the Co–W–Cl System

Influence of the Diphosphine Coordinated to Molybdenum and Tungsten Triangular M$_{3}$S$_{4}$ Cluster Hydrides in the Catalytic Hydrodefluorination of Pentafluoropyridine

Photoinduced Electron Transfer Reactions of Hexarhenium(III) Cluster: Oxidative Quenching of [Re$_{6}$S$_{8}$Cl$_{6}$]$^{4−}$ Emission by Electron Acceptors

Syntheses, Structures, and Luminescence Properties of New Octahedral Cluster Complexes with Terminal Phenolate Ligands: [K(H$_{2}$O)(CH$_{3}$OH)$_{3}$]$_{2}$[Ph$_{4}$P]$_{2}$[M $_{6}$Cl$_{12}$(O–C$_{6}$H$_{4}$–F)$_{6}$] (M = Nb, Ta; Ph = phenyl)

Alkynyl-Phosphine Substituted Fe$_{2}$S$_{2}$ Clusters: Synthesis, Structure and Spectroelectrochemical Characterization of a Cluster with a Class III Mixed-Valence [FeFe]$^{3+}$ Core

Synthesis and Molecular Structure of Redox Active Platinum–Bis(Telluroferrocenyl) Complex and its Chelated Rhenium-Chloro(Tricarbonyl) Derivative

Reactions of K$_{2}$[Fe$_{3}$Q(CO)$_{9}$] (Q = Se, Te) with AsI$_{3}$: Synthesis and Structures of the First {Fe$_{3}$TeAs} Clusters with Capping µ$_{3}$-AsI and Bridging µ$_{6}$,κ$^{3}$:κ$^{3}$-As$_{2}$ Ligands

[Nb$_{3}$(µ$_{3}$-Cl)(µ-Cl)$_{3}$(CH$_{3}$CN)$_{9}$] (GaCl$_{4}$)$_{4}$, A Discrete, Seven Valence Electron Triniobium Cluster Derivative of Nb$_{3}$Cl$_{8}$

[Re$_{6}$(μ$_{3}$-Se)$_{8}$]$^{2+}$ Core-Containing Cluster Complexes with Isonicotinic Acid: Synthesis, Structural Characterization, and Hydrogen-Bonded Assemblies

Synthesis, Characterization and Crystal Structures of Some Metal Carbonyl Linking Clusters of Osmium, Ruthenium and Cobalt Derived from Diethynylarenes

Journal of Cluster Science : Volume 25

Journal of Cluster Science : Volume 24

Journal of Cluster Science : Volume 23

Journal of Cluster Science : Volume 22

Journal of Cluster Science : Volume 21

Journal of Cluster Science : Volume 20

Journal of Cluster Science : Volume 19

Journal of Cluster Science : Volume 18

Journal of Cluster Science : Volume 17

Journal of Cluster Science : Volume 16

Journal of Cluster Science : Volume 15

Journal of Cluster Science : Volume 14

Journal of Cluster Science : Volume 13

Journal of Cluster Science : Volume 12

Journal of Cluster Science : Volume 11

Journal of Cluster Science : Volume 10

Journal of Cluster Science : Volume 9

Journal of Cluster Science : Volume 8

Reactions of K$_{2}$[Fe$_{3}$Q(CO)$_{9}$] (Q = Se, Te) with AsI$_{3}$: Synthesis and Structures of the First {Fe$_{3}$TeAs} Clusters with Capping µ$_{3}$-AsI and Bridging µ$_{6}$,κ$^{3}$:κ$^{3}$-As$_{2}$ Ligands

Content Provider	Springer Nature Link
Author	Ilyin, Igor Yu. Konchenko, Sergey N. Pushkarevsky, Nikolay A.
Copyright Year	2014
Abstract	Reactions of cluster salts K$_{2}$[Fe$_{3}$Q(CO)$_{9}$] (Q = Se, Te) with AsI$_{3}$ in CH$_{2}$Cl$_{2}$ proceed differently depending on the chalcogen atom and the reaction conditions. For Te, the product of addition of μ$_{3}$-AsI vertex to the initial cluster, [Fe$_{3}$(CO)$_{9}$(μ$_{3}$-Te)(μ$_{3}$-AsI)] (2b) is the main component of the solution. By action of traces of water, such as wet silica gel, 2b is converted to a dimeric cluster [{Fe$_{3}$(CO)$_{9}$(μ$_{3}$-Te)}$_{2}$(μ$_{6}$,κ$^{3}$:κ$^{3}$-As$_{2}$)] (5), whose molecules contain two identical square-pyramidal cores joined by diarsane moiety. For Se, the product 2a, analogous to 2b, was only found on the basis of mass-spectra, as main component of the reaction solution, but could not be separated because of its instability and similarity of its properties to those of [Fe$_{3}$(CO)$_{9}$Se$_{2}$], a by-product. Two other products, [Fe$_{3}$(CO)$_{9}$(μ$_{3}$-Se)(µ$_{4}$,κ$^{3}$:κ$^{2}$-AsSe)Fe$_{2}$(CO)$_{6}$(μ-I)] (3) and K[{Fe$_{3}$(CO)$_{9}$(μ$_{3}$-Se)(μ$_{4}$-As)}$_{2}$Fe(CO)$_{3}$I] (4) were only found as little amount of crystals. The molecule of 3 consists of the pyramidal {Fe$_{3}$SeAs} core linked by the As–Se bond to a {Fe$_{2}$SeI} fragment. The cluster anion in 4 consists of two {Fe$_{3}$SeAs} cores joined via the {Fe(CO)$_{3}$I} unit. The products 3 and 4 presumably originate from the dissociation of the initial cluster core and their formation correlates with lower stability of Se-containing cluster 2a as compared to 2b.
Starting Page	257
Ending Page	268
Page Count	12
File Format	PDF
ISSN	10407278
Journal	Journal of Cluster Science
Volume Number	26
Issue Number	1
e-ISSN	15728862
Language	English
Publisher	Springer US
Publisher Date	2014-08-24
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Carbonyl clusters Iron Selenium Tellurium Arsenic Reactivity Catalysis Inorganic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Biochemistry Condensed Matter Physics Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis, Structure and Isomerism of the [Fe$_{3}$Pt(μ$_{4}$-Q)(CO)$_{9}$(dppm)] Clusters (Q = Se, Te; dppm = Ph$_{2}$PCH$_{2}$PPh$_{2}$)

Synthesis and structures of new heteronuclear cluster complexes [PPh$_{4}$][Fe$_{4}$Rh$_{3}$Se$_{2}$(CO)$_{16}$] and [PPh$_{4}$]$_{2}$[Fe$_{3}$Rh$_{4}$Te$_{2}$(CO)$_{15}$]

Synthesis and structure of the cluster Fe$_{2}$Mo$_{2}$(μ$_{3}$-Se)(μ$_{3}$-AsMe)(μ$_{3}$-Co)(μ-Co)(Co)$_{5}$(η$^{5}$-Cp)$_{2}$

Isolobal replacement of the metal fragments in [Fe$_{3}$(μ$_{3}$-Q)(μ$_{3}$-AsCH$_{3}$)(CO)$_{9}$] (Q = Se and Te): Synthesis and structures of a number of Fe-Ir and Fe-Rh clusters simultaneously containing a chalcogen and arsenic

New Main-Group-Element-Rich nido-Octahedral Cluster System: Synthesis and Characterization of [Et4N][Fe-2(CO)(6)(μ(3)-As)μ(3)-EFe(CO)(4)(2)]

Synthesis of clusters Fe$_{2}$(CO)$_{6}$(μ-XCH$_{2}$CH=CH$_{2}$)(μ$_{3}$-X)Fe(CO)$_{2}$Cp (X = Se, S; Cp = η$^{5}$-C$_{5}$H$_{5}$)

Activation of elemental S, Se and Te with uranium(iii): bridging U–E–U (E = S, Se) and diamond-core complexes U–(E)₂–U (E = O, S, Se, Te)

Alane reduction of selenium and tellurium: tertiary amine stabilised dimeric chalcogenides, trans-[{Me₃N(H)Al(µ-E)}₂](E = Se, Te)

Isomerism of [FeMM′(µ$_{3}$-Q)(CO)$_{7}$CpCp′] heterometallic clusters (Q = Se, Te; M, M′ = Mo, W; Cp = η$^{5}$-C$_{5}$H$_{5}$; Cp′ = Cp, η$^{5}$-C$_{5}$(CH$_{3}$)$_{5}$) in solids

Reactions of K$_{2}$[Fe$_{3}$Q(CO)$_{9}$] (Q = Se, Te) with AsI$_{3}$: Synthesis and Structures of the First {Fe$_{3}$TeAs} Clusters with Capping µ$_{3}$-AsI and Bridging µ$_{6}$,κ$^{3}$:κ$^{3}$-As$_{2}$ Ligands

Similar Documents

Synthesis, Structure and Isomerism of the [Fe$_{3}$Pt(μ$_{4}$-Q)(CO)$_{9}$(dppm)] Clusters (Q = Se, Te; dppm = Ph$_{2}$PCH$_{2}$PPh$_{2}$)

Synthesis and structures of new heteronuclear cluster complexes [PPh$_{4}$][Fe$_{4}$Rh$_{3}$Se$_{2}$(CO)$_{16}$] and [PPh$_{4}$]$_{2}$[Fe$_{3}$Rh$_{4}$Te$_{2}$(CO)$_{15}$]

Synthesis and structure of the cluster Fe$_{2}$Mo$_{2}$(μ$_{3}$-Se)(μ$_{3}$-AsMe)(μ$_{3}$-Co)(μ-Co)(Co)$_{5}$(η$^{5}$-Cp)$_{2}$

Isolobal replacement of the metal fragments in [Fe$_{3}$(μ$_{3}$-Q)(μ$_{3}$-AsCH$_{3}$)(CO)$_{9}$] (Q = Se and Te): Synthesis and structures of a number of Fe-Ir and Fe-Rh clusters simultaneously containing a chalcogen and arsenic

New Main-Group-Element-Rich nido-Octahedral Cluster System: Synthesis and Characterization of [Et4N][Fe-2(CO)(6)(μ(3)-As)μ(3)-EFe(CO)(4)(2)]

Synthesis of clusters Fe$_{2}$(CO)$_{6}$(μ-XCH$_{2}$CH=CH$_{2}$)(μ$_{3}$-X)Fe(CO)$_{2}$Cp (X = Se, S; Cp = η$^{5}$-C$_{5}$H$_{5}$)

Activation of elemental S, Se and Te with uranium(iii): bridging U–E–U (E = S, Se) and diamond-core complexes U–(E)2–U (E = O, S, Se, Te)

Alane reduction of selenium and tellurium: tertiary amine stabilised dimeric chalcogenides, trans-[{Me3N(H)Al(µ-E)}2](E = Se, Te)

Isomerism of [FeMM′(µ$_{3}$-Q)(CO)$_{7}$CpCp′] heterometallic clusters (Q = Se, Te; M, M′ = Mo, W; Cp = η$^{5}$-C$_{5}$H$_{5}$; Cp′ = Cp, η$^{5}$-C$_{5}$(CH$_{3}$)$_{5}$) in solids

Reactions of K$_{2}$[Fe$_{3}$Q(CO)$_{9}$] (Q = Se, Te) with AsI$_{3}$: Synthesis and Structures of the First {Fe$_{3}$TeAs} Clusters with Capping µ$_{3}$-AsI and Bridging µ$_{6}$,κ$^{3}$:κ$^{3}$-As$_{2}$ Ligands

Activation of elemental S, Se and Te with uranium(iii): bridging U–E–U (E = S, Se) and diamond-core complexes U–(E)₂–U (E = O, S, Se, Te)

Alane reduction of selenium and tellurium: tertiary amine stabilised dimeric chalcogenides, trans-[{Me₃N(H)Al(µ-E)}₂](E = Se, Te)