NDLI: Syntheses, Structures and Third-Order Nonlinear Optical Properties of Two-Dimensional Rhombohedral Grid Coordination Polymers: [Cd(imz)$_{3}$]$_{2}$(BTC)·0.5H$_{2}$O and [Cu$_{4}$(H$_{2}$O)$_{2}$(imz)$_{8}$](BTC)$_{2}$·7H$_{2}$O(BTC = 1, 2, 4, 5-benzenetetracarboxylate anion, imz = imidazole)

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Syntheses, Structures and Third-Order Nonlinear Optical Properties of Two-Dimensional Rhombohedral Grid Coordination Polymers: [Cd(imz)$_{3}$]$_{2}$(BTC)·0.5H$_{2}$O and [Cu$_{4}$(H$_{2}$O)$_{2}$(imz)$_{8}$](BTC)$_{2}$·7H$_{2}$O(BTC = 1, 2, 4, 5-benzenetetracarboxylate anion, imz = imidazole)

Content Provider	Springer Nature Link
Author	An, Caixia Feng, Xilan Zhao, Ning Liu, Ping Wang, Tianxi Lian, Zhaoxun
Copyright Year	2014
Abstract	Hydrothermal reactions of 1, 2, 4, 5-benzenetetracarboxylic acid (H$_{4}$BTC) with cadmium acetate and copper acetate in the presence of imidazole (imz) resulted in two new coordination polymers, namely, [Cd(imz)$_{3}$]$_{2}$(BTC)·0.5H$_{2}$O 1, [Cu$_{4}$(H$_{2}$O)$_{2}$(imz)$_{8}$](BTC)$_{2}$·7H$_{2}$O 2. Two compounds have been characterized structurally using single-crystal diffraction, elemental analysis, and FT-IR spectrum. In compound 1, the hexa-coordinated Cd(II) ions are bridged by BTC to form two-dimensional rhombohedral grid sheets. In compound 2, the coordination polyhedrons [CuO$_{4}$N$_{2}$] and [CuO$_{3}$N$_{2}$] are bridged by BTC to lead to a 2D framework with rectangular-shaped cavities. Two compounds of third-order nonlinear optical (NLO) properties were determined by Z-scan technique in DMSO solution. The results showed that two compounds exhibited strong NLO absorption and strong self-focusing effects. The third-order NLO absorptive coefficients β(MKS) are 5.45 × 10$^{−11}$ m W$^{−1}$ for 1 and 9.81 × 10$^{−11}$ m W$^{−1}$ for 2. The refractive indexes γ(MKS) are 3.96 × 10$^{−18}$ m$^{2}$ W$^{−1}$ for 1 and 7.60 × 10$^{−18}$ m$^{2}$ W$^{−1}$ for 2. The third-order NLO susceptibility χ$^{(3)}$ are calculated to be 1.25 × 10$^{−11}$ for 1, 2.32 × 10$^{−11}$ esu for 2, respectively. These values are larger than those of metal coordination polymers reported.Two novel two-dimensional transition metal coordination polymers have been reported. Two compounds exhibit strong NLO absorption and strong self-focusing effects. The third-order NLO susceptibility χ$^{(3)}$ are calculated to be 1.25 × 10$^{−11}$ for 1, 2.32 × 10$^{−11}$ esu for 2, respectively
Starting Page	889
Ending Page	900
Page Count	12
File Format	PDF
ISSN	10407278
Journal	Journal of Cluster Science
Volume Number	26
Issue Number	3
e-ISSN	15728862
Language	English
Publisher	Springer US
Publisher Date	2014-08-17
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Third-order nonlinear optics Z-scan Transition metal Crystal structure Coordination polymer Catalysis Inorganic Chemistry Physical Chemistry Nanochemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Biochemistry Condensed Matter Physics Materials Science

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Investigation on Third-Order Nonlinear Optical Properties of Four Transition Metal Complexes Thin Films by Z-Scan Technique

Syntheses and structures of seven-coordinate K$_{3}$[Cd(Dtpa)], K$_{2}$[Cd(H$_{2}$O)$_{4}$][Cd(Edta)(H$_{2}$O)]$_{2}$ · 2H$_{2}$O, and Na$_{2}$[Cd(H$_{2}$O)$_{4}$][Cd(Edta)(H$_{2}$O)]$_{2}$ · 2H$_{2}$O complexes

Syntheses, Crystal Structures and Third-order Nonlinear Optical Properties of Coordination Polymers {[Et$_{4}$N][Ag$_{2}$I$_{3}$]}$_{n}$ and [CuBr(C$_{10}$H$_{8}$N$_{2}$S$_{2}$)]$_{n }$

Syntheses, crystal structures and properties of three novel coordination polymers with tripodal imidazole-containing ligands and benzenetetracarboxylate

Syntheses, crystal structures and properties of three novel coordination polymers with tripodal imidazole-containing ligands and benzenetetracarboxylate

Two novel one-dimensional coordination polymers [Cu$_{2}$(μ-Br)$_{2}$(pcaede)$_{2}$ · 2H$_{2}$O]$_{ n }$ and [Cu$_{2}$(μ-Br)$_{2}$(pcaede)$_{2}$ · 0.5THF · 0.5H$_{2}$O]$_{ n }$ formed via self-assembly of 4-pyridine-carboxylic acid 1,2-ethanediyl ester (pcaede) with copper(I) bromide

Improved femtosecond third-order nonlinear optical properties of thin layered Cu 3 Nb 2 O 8

Third-order nonlinear optical properties of the small-molecular organic semiconductor tris (8-Hydroxyquinoline) aluminum by CW Z-scan technique

A 2D organic-inorganic hybrid [Cu(En)$_{2}$(H$_{2}$O)]$_{2}$[Cu(En)$_{2}$]$_{4}$[Si$_{2}$Cu$_{2}$W$_{22}$O$_{78}$]·7H$_{2}$O assembled from monocopper(II)-substituted Keggin silicotungstate dimers

Syntheses, Structures and Third-Order Nonlinear Optical Properties of Two-Dimensional Rhombohedral Grid Coordination Polymers: [Cd(imz)$_{3}$]$_{2}$(BTC)·0.5H$_{2}$O and [Cu$_{4}$(H$_{2}$O)$_{2}$(imz)$_{8}$](BTC)$_{2}$·7H$_{2}$O(BTC = 1, 2, 4, 5-benzenetetracarboxylate anion, imz = imidazole)

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Syntheses, Structures and Third-Order Nonlinear Optical Properties of Two-Dimensional Rhombohedral Grid Coordination Polymers: [Cd(imz)$_{3}$]$_{2}$(BTC)·0.5H$_{2}$O and [Cu$_{4}$(H$_{2}$O)$_{2}$(imz)$_{8}$](BTC)$_{2}$·7H$_{2}$O(BTC = 1, 2, 4, 5-benzenetetracarboxylate anion, imz = imidazole)